{"id":"W2080588335","doi":"10.1021/ic0502980","title":"Structure, Bonding, and Reactivity of Ti and Zr Amidate Complexes:  DFT and X-Ray Crystallographic Studies","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Crystallography; Reactivity (psychology); X-ray; X-ray crystallography; Crystal structure; Diffraction","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00011683,0.0003002536,0.0005572049,0.00004474098,0.0001307737,0.00004888965,0.0001603313,0.0001449219,0.001907152],"category_scores_gemma":[0.0001174849,0.0002834844,0.00006226548,0.0001697801,0.0005120808,0.0001278357,0.0003168558,0.0002095841,6.753158e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000040318,"about_ca_system_score_gemma":0.00002304042,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002590118,"about_ca_topic_score_gemma":0.00003599512,"domain_scores_codex":[0.9986572,0.00001171538,0.0003624493,0.000513224,0.0002006648,0.0002547897],"domain_scores_gemma":[0.9989933,0.0001639587,0.0002258929,0.00042579,0.0000599138,0.0001311222],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001328028,0.00005071751,0.006383694,0.000621144,0.0002762945,0.0000025173,0.0003733516,2.1971e-7,0.9869742,0.00003760205,0.00004988168,0.005217068],"study_design_scores_gemma":[0.000624426,0.00001166364,0.01065327,0.00009718505,0.0002762281,0.0001006404,0.001293796,0.00003556186,0.9744953,0.000508323,0.01147797,0.0004256259],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910402,0.007228822,0.000002928916,0.0001744891,0.0000103213,0.00003963411,0.000114252,0.00005422456,0.00133516],"genre_scores_gemma":[0.997771,0.0008873563,0.0002300808,0.00002270215,0.0001230513,0.000003616627,0.00002471708,0.00003074065,0.0009067848],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01247892,"threshold_uncertainty_score":0.9999617,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01388725748136574,"score_gpt":0.2373415909493841,"score_spread":0.2234543334680184,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}