{"id":"W2081184441","doi":"10.1002/ejic.200801169","title":"N‐Heterocyclic Carbene Rhodium Complexes and Their Reactions with H<sub>2</sub> and with CO","year":2009,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"IMes; Carbene; Chemistry; Medicinal chemistry; Rhodium; Hexane; Cyclooctene; Isomerization; Catalysis; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002542912,0.0005749588,0.0006325171,0.00004734474,0.0002408732,0.0001563538,0.0004578773,0.0001246727,0.0002647899],"category_scores_gemma":[0.00007176493,0.0004284761,0.0001051975,0.0001789145,0.0003884487,0.0002334769,0.0001125976,0.0009688783,0.000005052428],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000139671,"about_ca_system_score_gemma":0.00009520884,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002240501,"about_ca_topic_score_gemma":0.000001289587,"domain_scores_codex":[0.9977938,0.00004700916,0.0008067081,0.0005159546,0.0003721847,0.0004643552],"domain_scores_gemma":[0.99786,0.0001143958,0.0007785659,0.0005869868,0.000189227,0.0004708347],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002182978,0.0001145553,0.0007983199,0.0001882972,0.000184517,0.0002329664,0.000363237,0.000002175485,0.9942395,0.000003499616,0.0003857552,0.003268871],"study_design_scores_gemma":[0.002274212,0.0002139042,0.001531643,0.0004285917,0.0001282703,0.01365389,0.0009955544,0.000005367729,0.9775148,0.00002832395,0.002698286,0.0005271803],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9821755,0.00110023,0.0001507368,0.0002956527,0.00003589437,0.00004594272,0.00002866254,0.00008710516,0.0160803],"genre_scores_gemma":[0.9979491,0.0007034049,0.0002181852,0.0001582191,0.0006345335,7.011782e-7,0.00001873232,0.0001059388,0.0002111765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01672473,"threshold_uncertainty_score":0.9998167,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006531363158540071,"score_gpt":0.1930249343259922,"score_spread":0.1864935711674522,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}