{"id":"W2081277202","doi":"10.1021/ja0604663","title":"High Hydride Count Rhodium Octahedra, [Rh<sub>6</sub>(PR<sub>3</sub>)<sub>6</sub>H<sub>12</sub>][BAr<sup>F</sup><sub>4</sub>]<sub>2</sub>: Synthesis, Structures, and Reversible Hydrogen Uptake under Mild Conditions","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Engineering and Physical Sciences Research Council; École Polytechnique Fédérale de Lausanne","keywords":"Chemistry; Hydride; Crystallography; Octahedron; Rhodium; Cluster (spacecraft); Nuclear magnetic resonance spectroscopy; Metal; Crystal structure; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006575118,0.000218444,0.0002368,0.0001407818,0.0001587371,0.0003779233,0.0005718305,0.0003250851,0.0009438904],"category_scores_gemma":[0.0001786753,0.0002094756,0.0001356891,0.0001537837,0.0001739275,0.0002784663,0.0002254299,0.0003793574,0.0005468738],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003846731,"about_ca_system_score_gemma":0.0002433804,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001368049,"about_ca_topic_score_gemma":0.002932462,"domain_scores_codex":[0.9998703,0.000009052655,0.000007086338,0.0000401023,0.00005507303,0.00001836887],"domain_scores_gemma":[0.9999218,0.000005903643,0.00002102861,0.000008962841,0.00002223145,0.00002002727],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00016929,0.00002435952,0.0002219173,0.0001328625,0.00001395666,0.00004301312,0.00003520747,0.0004728406,0.9923992,0.0005706297,0.0005033612,0.005413427],"study_design_scores_gemma":[0.00004528941,0.0004312659,0.002496573,0.000006921499,0.00003445926,0.0003451796,0.00004454527,0.003715733,0.9759321,0.0002251587,0.0166939,0.00002898091],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9740682,0.001189103,0.01631893,0.0001414144,0.00006844111,0.0001283591,0.0007106488,0.0008512505,0.006523596],"genre_scores_gemma":[0.9661521,0.0005641319,0.02441251,0.00008541284,0.0000195047,0.00009409159,0.0009911607,0.0001516377,0.007529542],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001368049,"threshold_uncertainty_score":0.003157675,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006983166990620546,"score_gpt":0.2068447305122708,"score_spread":0.1998615635216502,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}