{"id":"W2081329585","doi":"10.1002/ejic.201300583","title":"The Effect of Aryl Substitution on the Properties of a Series of Highly Absorptive Cationic Iridium(III) Complexes Bearing Ancillary Bis(arylimino)acenaphthene Ligands","year":2013,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Université de Sherbrooke; Bowling Green State University","keywords":"Chemistry; Iridium; Acenaphthene; Ligand (biochemistry); Cationic polymerization; Aryl; Absorption spectroscopy; Cyclic voltammetry; Photochemistry; Substituent; Absorption (acoustics); Medicinal chemistry; Electrochemistry; Physical chemistry; Alkyl; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00122152,0.0002108546,0.0003688684,0.0000533968,0.0001186064,0.00004483479,0.0006846972,0.0000446639,0.00005643803],"category_scores_gemma":[0.0005065198,0.0001190752,0.0001378837,0.0002719077,0.0003684851,0.0001679195,0.0001207957,0.0004534948,0.00001034299],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001150412,"about_ca_system_score_gemma":0.0001115643,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001019176,"about_ca_topic_score_gemma":6.929187e-7,"domain_scores_codex":[0.9982458,0.00009575417,0.0008119242,0.0001198905,0.0004835072,0.000243165],"domain_scores_gemma":[0.9983385,0.0003139866,0.0004736583,0.0004338531,0.0003677658,0.000072195],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001022324,0.00002308083,0.0005930736,0.0004177532,0.0001964507,0.000005642263,0.0006562619,0.0001640061,0.9973494,0.00001936779,0.0003424344,0.0001302616],"study_design_scores_gemma":[0.0004873338,0.0002615036,0.00290772,0.0005470299,0.00003930846,0.00008515599,0.0002956979,0.0001169803,0.9950554,0.000004463361,0.00008983887,0.0001095246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965028,0.001800435,0.00001639461,0.0002102109,0.00009852962,0.0001776156,0.000005282955,0.00002497247,0.001163825],"genre_scores_gemma":[0.9992926,0.0003588901,0.00002657145,0.000004292137,0.000159946,0.000002420674,0.000001477455,0.00004887245,0.0001049344],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002789862,"threshold_uncertainty_score":0.4855745,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0107388382348028,"score_gpt":0.1865460285551802,"score_spread":0.1758071903203773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}