{"id":"W2081536589","doi":"10.1016/j.jms.2004.06.004","title":"Fourier transform spectroscopy of CH3OH: rotation–torsion–vibration structure for the CH3-rocking and OH-bending modes","year":2004,"lang":"en","type":"article","venue":"Journal of Molecular Spectroscopy","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":false,"ca_institutions":"Steacie Institute for Molecular Sciences; University of New Brunswick","funders":"National Research Council Canada; CH Foundation","keywords":"Torsion (gastropod); Excited state; Fourier transform; Physics; Dihedral angle; Spectral line; Torsional vibration; Vibration; Nuclear magnetic resonance; Molecular physics; Atomic physics; Molecule; Quantum mechanics; Hydrogen bond","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002312008,0.0002604064,0.000372516,0.0001400197,0.0003126287,0.000102318,0.0003471753,0.0001456794,0.0001423871],"category_scores_gemma":[0.00007114475,0.0001983431,0.0002534224,0.0002293397,0.0001180571,0.0002869041,0.00002413827,0.000417854,5.493933e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00019013,"about_ca_system_score_gemma":0.0001787048,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001855833,"about_ca_topic_score_gemma":0.00002423989,"domain_scores_codex":[0.9982683,0.00001664724,0.0006789195,0.0002472048,0.0004607733,0.0003281487],"domain_scores_gemma":[0.998654,0.0001083723,0.0006278292,0.0003233083,0.0001693565,0.0001171171],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002097916,0.00006616816,0.0001111419,0.00008959766,0.0001532243,0.000004959174,0.000492857,0.004330587,0.981519,0.01270635,0.00003176413,0.0002845089],"study_design_scores_gemma":[0.001496611,0.0002213767,0.000133972,0.000134557,0.0002415186,0.00008801855,0.0005428315,0.002382926,0.9724159,0.02177704,0.0003826091,0.0001826492],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7261639,0.001183476,0.2701663,0.001446199,0.0000939617,0.0002691037,0.00004007749,0.00002002602,0.0006170009],"genre_scores_gemma":[0.9451731,0.0002921907,0.05401504,0.0001019757,0.0003171108,0.00002063253,0.00001332292,0.00004453297,0.0000221251],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2190092,"threshold_uncertainty_score":0.8088198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006996890061924672,"score_gpt":0.2643685225379183,"score_spread":0.2573716324759937,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}