{"id":"W2081937595","doi":"10.1016/s0045-2068(02)00509-6","title":"Rates of release of nitric oxide from HbSNO and internal electron transfer","year":2003,"lang":"en","type":"article","venue":"Bioorganic Chemistry","topic":"Nitric Oxide and Endothelin Effects","field":"Medicine","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Nitric oxide; Thiol; Electron transfer; Hemoglobin; Reaction rate constant; Cysteine; Ferrous; Heme; Hemeprotein; Redox; Kinetics; Photochemistry; Inorganic chemistry; Biochemistry; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001877454,0.0004993125,0.0005577894,0.0002822046,0.0002299428,0.0005554259,0.0006055292,0.0005885224,0.002956964],"category_scores_gemma":[0.00280576,0.0002424445,0.0002837191,0.000295641,0.0005631367,0.000956114,0.0004061801,0.001438504,0.0004767374],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005866088,"about_ca_system_score_gemma":0.0002481475,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008683441,"about_ca_topic_score_gemma":0.0004549909,"domain_scores_codex":[0.9993825,0.0001502488,0.00003587132,0.00009184492,0.0001433992,0.0001961237],"domain_scores_gemma":[0.9973994,0.001423624,0.0002928943,0.0003480426,0.0003268977,0.0002091461],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.006756667,0.0002049432,0.003640099,0.0002969451,0.0001067417,0.0002285056,0.000524007,0.0007774384,0.9671791,0.002827204,0.0003415927,0.01711689],"study_design_scores_gemma":[0.00007748598,0.0003968529,0.007798178,0.000016716,0.00003582374,0.0001100244,0.00008686356,0.002485645,0.9878272,0.0002683561,0.0008758246,0.00002107713],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870915,0.001829784,0.006776569,0.00009779014,0.0001061776,0.00008360463,0.0005083362,0.0000824634,0.003423869],"genre_scores_gemma":[0.9929559,0.000593883,0.001512345,0.00005017071,0.00003446318,0.00006590797,0.0007910805,0.00003704917,0.003959156],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002956964,"threshold_uncertainty_score":0.009929061,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007882077624519744,"score_gpt":0.2321836893269233,"score_spread":0.2243016117024036,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}