{"id":"W2082045735","doi":"10.1021/jo035439z","title":"Photochemical Pinacol Rearrangements of Unsymmetrical Diols","year":2004,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; Steacie Institute for Molecular Sciences; York University","funders":"","keywords":"Pinacol; Photochemistry; Chemistry; Product distribution; Substituent; Flash photolysis; Carbocation; Catalysis; Kinetic energy; Medicinal chemistry; Organic chemistry; Kinetics; Reaction rate constant","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001423904,0.0003591387,0.0001497771,0.0001934574,0.0001547278,0.0001628112,0.0002814321,0.0002810894,0.002053857],"category_scores_gemma":[0.0002359085,0.0001198314,0.0001681777,0.0002087487,0.000246565,0.0003436582,0.0001976567,0.0003930531,0.0002876198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002568098,"about_ca_system_score_gemma":0.0001517261,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005703239,"about_ca_topic_score_gemma":0.001285552,"domain_scores_codex":[0.999842,0.00002176064,0.00000617774,0.00003408318,0.00002962124,0.00006617115],"domain_scores_gemma":[0.9998727,0.0000329867,0.00004014234,0.00001555521,0.00001630075,0.00002221476],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001807412,0.00002180491,0.0001474346,0.00006936666,0.000008676817,0.00009890831,0.00005982301,0.0002934212,0.9961964,0.0004455603,0.00003955131,0.002438352],"study_design_scores_gemma":[0.000008734021,0.0002891541,0.001143243,0.000002486636,0.000006753108,0.00009602831,0.0000247541,0.0002699457,0.9971473,0.00005275418,0.0009522201,0.000006649108],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957,0.0005060454,0.001048653,0.00003098863,0.00001188106,0.00001722383,0.0001023976,0.00001970877,0.002563116],"genre_scores_gemma":[0.9978655,0.0003402654,0.0004308647,0.00001883586,0.000003444689,0.000008664755,0.00008610952,0.000008638938,0.001237729],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002053857,"threshold_uncertainty_score":0.006870806,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.011585524460724,"score_gpt":0.2422535039654504,"score_spread":0.2306679795047264,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}