{"id":"W2082196235","doi":"10.1021/ic9012284","title":"Phosphines Bearing Alkyne Substituents: Synthesis and Hydrophosphination Polymerization","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Alkyne; Bearing (navigation); Polymerization; Polymer chemistry; Organic chemistry; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0000921153,0.000340143,0.0003309925,0.00004182632,0.0002155747,0.0001685481,0.000315592,0.0002276379,0.006580889],"category_scores_gemma":[0.0003075858,0.0003683323,0.00007533447,0.000314654,0.00007459196,0.0002898854,0.00008182897,0.0001908239,0.00002849471],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001267372,"about_ca_system_score_gemma":0.00005640865,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001644376,"about_ca_topic_score_gemma":0.000001013944,"domain_scores_codex":[0.9983352,0.000007519624,0.0004621912,0.0005435788,0.0003285505,0.0003229246],"domain_scores_gemma":[0.9989449,0.00009677094,0.0002414623,0.0004611901,0.00009003967,0.0001655914],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001624452,0.0001401446,0.002537174,0.00007543901,0.00003978836,0.000006699207,0.0001071031,0.000001391197,0.9876004,0.00007520305,0.00004110203,0.009359347],"study_design_scores_gemma":[0.0003174976,0.000006952134,0.009521576,0.00008896,0.00006355349,0.00007089345,0.00009582678,0.0002582821,0.9876678,0.0001665809,0.001329045,0.0004130457],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9904131,0.0004845308,0.0001715538,0.0008400494,0.00006798393,0.00004686932,0.00002074296,0.0002803826,0.007674755],"genre_scores_gemma":[0.9974307,0.0002985446,0.0001108063,0.0001892296,0.0003137166,0.000009929518,0.00009300151,0.00004885482,0.001505166],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008946301,"threshold_uncertainty_score":0.9998769,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006965178788599301,"score_gpt":0.2010255673739499,"score_spread":0.1940603885853506,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}