{"id":"W2082204707","doi":"10.1021/om7006437","title":"Exploring the Utility of Neutral Rhodium and Iridium κ<sup>2</sup>-<i>P</i>,<i>O</i>and κ<sup>2</sup>-P(<i>S</i>),<i>O</i>Complexes as Catalysts for Alkene Hydrogenation and Hydrosilylation","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Alberta; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Iridium; Catalysis; Rhodium; Indene; Cyclooctadiene; Triethylsilane; Yield (engineering); Medicinal chemistry; Hydrolysis; Nuclear chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001276888,0.0004628172,0.0005943273,0.000342589,0.0004635094,0.0001334002,0.0003141844,0.0002038583,0.00008642323],"category_scores_gemma":[0.0003917124,0.0004077705,0.0001876369,0.0009521261,0.0003905127,0.0006464007,0.0002311249,0.0002785743,0.000007770735],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000672794,"about_ca_system_score_gemma":0.00007018094,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001600092,"about_ca_topic_score_gemma":0.00003813595,"domain_scores_codex":[0.9971974,0.00005425857,0.0009006646,0.0007726508,0.0005002641,0.0005747695],"domain_scores_gemma":[0.9978028,0.0006712014,0.0003777208,0.0006099318,0.0002365439,0.0003018172],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001692056,0.002090664,0.05755659,0.004266675,0.003316198,0.00004787492,0.03639898,0.002790312,0.6440315,0.0141571,0.001445675,0.2322063],"study_design_scores_gemma":[0.002400742,0.0001198024,0.005473117,0.00005124914,0.0007105431,0.0001186474,0.002550529,0.03175145,0.9387379,0.001194435,0.0160496,0.0008419317],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943065,0.001235368,0.00096413,0.0004865013,0.0000440252,0.0004085737,0.0001291863,0.0001038869,0.002321851],"genre_scores_gemma":[0.9975553,0.0006686905,0.0005160468,0.0001765139,0.0001976585,0.00006890633,0.0003402376,0.00007386309,0.0004028424],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2947064,"threshold_uncertainty_score":0.9998374,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03547297728275196,"score_gpt":0.2490413401754179,"score_spread":0.213568362892666,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}