{"id":"W2082242833","doi":"10.1016/j.chroma.2009.11.065","title":"A model for predicting slopes S in the basic equation for the linear-solvent-strength theory of peptide separation by reversed-phase high-performance liquid chromatography","year":2009,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; University of Manitoba","keywords":"Chemistry; Peptide; Trifluoroacetic acid; Chromatography; Reversed-phase chromatography; High-performance liquid chromatography; Phase (matter); Elution; Solvent; Analytical Chemistry (journal); Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001722307,0.001264202,0.001090325,0.0007788575,0.0005044028,0.0009339267,0.002089368,0.001819992,0.002821698],"category_scores_gemma":[0.006856004,0.000538129,0.00106589,0.000851192,0.0005410244,0.001933279,0.0004366427,0.002007982,0.002286013],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001129329,"about_ca_system_score_gemma":0.001198996,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004513163,"about_ca_topic_score_gemma":0.003150043,"domain_scores_codex":[0.9995118,0.0001375809,0.00003128972,0.0001440347,0.0001228794,0.00005237073],"domain_scores_gemma":[0.9979512,0.001462118,0.0001466724,0.00008670018,0.0003135412,0.00003977912],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0002074111,0.0003679502,0.005689386,0.0005709087,0.0002656575,0.0003278762,0.0002225234,0.8008484,0.02627231,0.06043995,0.009294957,0.09549266],"study_design_scores_gemma":[0.00002001053,0.00005341349,0.000597216,0.00001369923,0.00002983912,0.00007505868,0.000007636938,0.9861794,0.001783765,0.01001515,0.001201127,0.00002383428],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.0228466,0.000568496,0.972202,0.0005754189,0.0001554698,0.0001480385,0.000390364,0.0009336026,0.002180008],"genre_scores_gemma":[0.7083123,0.001964725,0.2707766,0.0008010158,0.0002069485,0.001030906,0.001231823,0.0003982877,0.01527741],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.004513163,"threshold_uncertainty_score":0.009439468,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02130179420262914,"score_gpt":0.2827524432816779,"score_spread":0.2614506490790487,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}