{"id":"W2082310938","doi":"10.1021/ja003860o","title":"Conrotatory Photochemical Ring Opening of Alkylcyclobutenes in Solution. A Test of the Hot Ground-State Mechanism","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Conrotatory and disrotatory; Ground state; Excited state; Reaction rate constant; Ring (chemistry); Singlet state; Rydberg formula; Quantum yield; Atomic physics; Computational chemistry; Photochemistry; Kinetics; Quantum mechanics; Fluorescence; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003025595,0.0002078168,0.0005945684,0.00001165536,0.00009375755,0.0000105827,0.0008767787,0.0000769279,0.00003033003],"category_scores_gemma":[0.0002222352,0.0001349271,0.0007228244,0.0004035605,0.00084894,0.00007679777,0.0002221685,0.00076346,1.927631e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002167439,"about_ca_system_score_gemma":0.0001382751,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001521058,"about_ca_topic_score_gemma":0.000003860984,"domain_scores_codex":[0.9982328,0.00002989295,0.0007351373,0.0001780943,0.000462605,0.0003614738],"domain_scores_gemma":[0.9983338,0.0002932945,0.0008480076,0.0003040463,0.0001468296,0.00007406895],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001207478,0.0001815397,0.008532723,0.00008363587,0.0001648785,0.00000245633,0.0006903022,0.00001390665,0.9898118,0.000006747359,0.000257722,0.0001335076],"study_design_scores_gemma":[0.0007540241,0.00002614332,0.001150675,0.0002564642,0.00007266155,0.0001110444,0.0008829628,0.0001396412,0.995805,0.0005010713,0.0001569211,0.0001433956],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986781,0.0002333885,0.00007352376,0.0005469154,0.00003910571,0.00008006561,0.00001507178,0.000007858836,0.0003260066],"genre_scores_gemma":[0.9989324,0.0003240549,0.0003683025,0.0002009363,0.00008374442,0.0000109572,5.720291e-7,0.00001773049,0.00006131141],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007382049,"threshold_uncertainty_score":0.5502169,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01145454175883859,"score_gpt":0.2401592194952711,"score_spread":0.2287046777364325,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}