{"id":"W2082388329","doi":"10.1021/om050053v","title":"Substituents Effects in POP Pincer Complexes of Ruthenium","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; University of Toronto","funders":"","keywords":"Chemistry; Agostic interaction; Ruthenium; Steric effects; Ligand (biochemistry); Pincer movement; Crystal structure; Stereochemistry; Medicinal chemistry; Crystallography; Catalysis; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001754379,0.0002833741,0.0006089393,0.0002330875,0.00005340231,0.00003207548,0.0005252463,0.0001274633,0.03122337],"category_scores_gemma":[0.0001187552,0.0002736293,0.0002107546,0.0006407214,0.0001307223,0.0001707568,0.0001576807,0.0001767092,0.0002476708],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001277129,"about_ca_system_score_gemma":0.00004733654,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006762649,"about_ca_topic_score_gemma":0.000152804,"domain_scores_codex":[0.99822,0.00002860708,0.0005813271,0.0004040407,0.000370119,0.0003959626],"domain_scores_gemma":[0.9987982,0.0001682116,0.0002032838,0.0006558747,0.00005454165,0.000119903],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003386797,0.0008379561,0.01272139,0.0003868674,0.0002098947,0.00001076362,0.0004697065,0.00006698842,0.9421823,0.004588081,0.00004801874,0.03844417],"study_design_scores_gemma":[0.001711706,0.00003407295,0.04323166,0.0001497031,0.0002414797,0.00001689387,0.0001994168,0.0004625888,0.8720506,0.0007340701,0.08032689,0.0008408857],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9748046,0.0009149702,0.000115571,0.0001626565,0.00005628125,0.00008623704,0.00003331128,0.00006442019,0.02376193],"genre_scores_gemma":[0.9949847,0.00008637695,0.001052194,0.0000583987,0.0001500587,0.00001777285,0.00005030996,0.00005223712,0.003547932],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08027887,"threshold_uncertainty_score":0.9999716,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009471557408850256,"score_gpt":0.223058508030039,"score_spread":0.2135869506211888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}