{"id":"W2082388329","doi":"10.1021/om050053v","title":"Substituents Effects in POP Pincer Complexes of Ruthenium","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; University of Toronto","funders":"","keywords":"Chemistry; Agostic interaction; Ruthenium; Steric effects; Ligand (biochemistry); Pincer movement; Crystal structure; Stereochemistry; Medicinal chemistry; Crystallography; Catalysis; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001529368,0.0004858688,0.0003617824,0.0001480303,0.0001659737,0.0005389477,0.000535575,0.0003280963,0.003016895],"category_scores_gemma":[0.0004214865,0.0003093445,0.0001770023,0.0001340686,0.000210008,0.0002852864,0.0005667609,0.0003326525,0.0005493401],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003288591,"about_ca_system_score_gemma":0.0001567554,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005057515,"about_ca_topic_score_gemma":0.0006849685,"domain_scores_codex":[0.9998022,0.00003522353,0.00001271884,0.00003639176,0.00003794393,0.00007559204],"domain_scores_gemma":[0.9998987,0.00002644701,0.00002557286,0.0000141048,0.00001269831,0.00002238676],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008967635,0.00004403043,0.0002278689,0.0001666779,0.00002996758,0.0002813381,0.00006404124,0.0008516004,0.9912283,0.0009247817,0.0002187902,0.005065717],"study_design_scores_gemma":[0.00004519973,0.0004242833,0.0003214215,0.000008543803,0.00002201675,0.0001445633,0.00002097049,0.0006814265,0.9954082,0.00006439126,0.002847504,0.00001137214],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930363,0.0007999739,0.0009139152,0.00006945123,0.00003348023,0.00003101339,0.00008953274,0.0001658642,0.004860303],"genre_scores_gemma":[0.996454,0.0003572061,0.0005850252,0.0000670867,0.00000689846,0.00001696447,0.0001155765,0.00003849865,0.002358725],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003016895,"threshold_uncertainty_score":0.0100925,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009471557408850256,"score_gpt":0.223058508030039,"score_spread":0.2135869506211888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}