{"id":"W2082525606","doi":"10.1139/v05-263","title":"Oxyhalogen-sulfur chemistry Kinetics and mechanism of the oxidation of cysteamine by acidic iodate and iodine","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; National Institutes of Health; National Science Foundation","keywords":"Chemistry; Iodate; Cysteamine; Stoichiometry; Iodine; Aqueous solution; Cystamine; Reaction rate constant; Inorganic chemistry; Kinetics; Reaction mechanism; Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001882504,0.0003288353,0.0002337172,0.0001905504,0.0001410787,0.0002116873,0.0003070002,0.0002410449,0.0009153921],"category_scores_gemma":[0.0002497682,0.0001477832,0.0003047033,0.00009959773,0.0002324817,0.0003482817,0.0001487819,0.0002188632,0.0002078349],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006910017,"about_ca_system_score_gemma":0.0002537348,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002305158,"about_ca_topic_score_gemma":0.001788936,"domain_scores_codex":[0.9999386,0.00001069065,0.000002859656,0.00001457181,0.00001728297,0.0000159276],"domain_scores_gemma":[0.9999371,0.00002327761,0.00001454297,0.000004462985,0.00001160624,0.000009140314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000258387,0.00003221453,0.00241011,0.000143241,0.00003180232,0.00009800654,0.00006576429,0.004253814,0.9874943,0.001287251,0.00005594628,0.003869209],"study_design_scores_gemma":[0.0000130386,0.0002448107,0.005479587,0.000007064113,0.00002321942,0.0001092613,0.00004583339,0.04032604,0.9523177,0.0003906284,0.001029506,0.00001327769],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912905,0.001018878,0.006350514,0.00004436446,0.000007363992,0.00002631858,0.00009804714,0.00006397334,0.001100021],"genre_scores_gemma":[0.9973344,0.0004162733,0.001338587,0.000005613668,0.000001404728,0.000009056005,0.00008516198,0.000007334735,0.0008023154],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002305158,"threshold_uncertainty_score":0.005013525,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004725763680487828,"score_gpt":0.1722611883191235,"score_spread":0.1675354246386357,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}