{"id":"W2082761298","doi":"10.1021/ic020167o","title":"Syntheses and X-ray Structures of Potassium Derivatives and a Paramagnetic Nickel(II) Complex of a Cyclodiphosph(III/V)azane Monoselenide","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Dimer; Octahedron; Crystallography; Comproportionation; Deprotonation; Nickel; Paramagnetism; Stereochemistry; Chelation; Crystal structure; Medicinal chemistry; Inorganic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007165271,0.0003531724,0.0007242181,0.00004153011,0.0001186342,0.00003136033,0.0003452233,0.0001777102,0.02769867],"category_scores_gemma":[0.0002854551,0.0003378632,0.0001153673,0.0002246335,0.0005938679,0.0000742285,0.0003251439,0.0001872765,0.000001877319],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002823892,"about_ca_system_score_gemma":0.00003120816,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009565392,"about_ca_topic_score_gemma":0.000006516115,"domain_scores_codex":[0.9982879,0.00001718816,0.0006128296,0.0004955446,0.0002822035,0.0003044058],"domain_scores_gemma":[0.9984372,0.0003297759,0.0003820133,0.0006164711,0.00007873161,0.000155861],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002666812,0.0001661148,0.001594916,0.0006862032,0.0002032675,0.000005100337,0.0007868971,0.000001868693,0.9895143,0.00005778258,0.00007516715,0.00688171],"study_design_scores_gemma":[0.000571271,0.00003212085,0.006454841,0.0001132076,0.000224677,0.00007706238,0.001161192,0.0002891075,0.9892564,0.0003257018,0.001110989,0.0003833626],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9880999,0.004767473,0.000007151702,0.0001599275,0.000009952621,0.00005871386,0.0001114596,0.00004545219,0.006739995],"genre_scores_gemma":[0.9974296,0.0005427704,0.0005061143,0.00001466606,0.00005420027,0.000008749975,0.00001746392,0.00003979724,0.001386601],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02769679,"threshold_uncertainty_score":0.9999073,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01678826949803323,"score_gpt":0.2061883443352024,"score_spread":0.1894000748371691,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}