{"id":"W2082856280","doi":"10.1063/1.481850","title":"An equilibrium supercooled liquid’s entropy and enthalpy in the Kauzmann and the third law extrapolations, and a proposed experimental resolution","year":2000,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Material Dynamics and Properties","field":"Materials Science","cited_by":91,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Thermodynamics; Enthalpy; Supercooling; Chemistry; Gibbs free energy; Extrapolation; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.005456681,0.0009100717,0.0006890049,0.00162641,0.0007188302,0.001675414,0.002700675,0.001169638,0.001663787],"category_scores_gemma":[0.0136903,0.0006902806,0.00104902,0.001327275,0.003953291,0.005583027,0.002666181,0.003233791,0.0003630376],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001521581,"about_ca_system_score_gemma":0.001088492,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001528941,"about_ca_topic_score_gemma":0.0008847396,"domain_scores_codex":[0.9971746,0.0007867469,0.0001653437,0.0008109983,0.0008663507,0.000195907],"domain_scores_gemma":[0.9964701,0.001464497,0.0004402581,0.001119769,0.0004251647,0.00008031378],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0008985194,0.0002086359,0.01591344,0.00116069,0.0001161164,0.000871114,0.001721544,0.02724651,0.271806,0.5865406,0.001347448,0.09216926],"study_design_scores_gemma":[0.00006892384,0.0006206649,0.0246377,0.0003330157,0.00007583098,0.001371706,0.000644264,0.1169886,0.5953428,0.2331791,0.02642353,0.0003139964],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.3246184,0.01169649,0.6236863,0.003067924,0.0004225982,0.0001560122,0.00099329,0.001311253,0.03404776],"genre_scores_gemma":[0.8978036,0.001844106,0.09752919,0.0003337412,0.0001188498,0.0002677209,0.0003681385,0.0001023264,0.001632396],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.005456681,"threshold_uncertainty_score":0.02885807,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01089571237185228,"score_gpt":0.2388310171654285,"score_spread":0.2279353047935763,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}