{"id":"W2082874131","doi":"10.1021/ja907613c","title":"Phosphinopnictonium Cations: High Yield and General Preparative Procedures for New Interpnictogen Frameworks Exploiting As→P and Sb→P Coordinate Bonds","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Dication; Ligand (biochemistry); Medicinal chemistry; Halide; Yield (engineering); Stereochemistry; Phosphorus; Ion; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001133235,0.0001851241,0.0003770945,0.00001339967,0.0001349071,0.000103689,0.0003020396,0.0001229227,0.0000902395],"category_scores_gemma":[0.0004871461,0.0001351934,0.000212401,0.0001527961,0.0001840949,0.0001479003,0.00009744239,0.0004200748,2.984924e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009411257,"about_ca_system_score_gemma":0.0001377815,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002804982,"about_ca_topic_score_gemma":5.01802e-7,"domain_scores_codex":[0.9989626,0.000008776876,0.0004274995,0.000207125,0.0001914775,0.0002025685],"domain_scores_gemma":[0.9984861,0.0002782645,0.000782043,0.0001726512,0.000136438,0.0001444989],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008292645,0.00006990426,0.000737057,0.00002063486,0.0001524184,3.027483e-7,0.001349125,0.000003306234,0.9905931,0.0001130477,0.003127211,0.003750952],"study_design_scores_gemma":[0.0005700075,0.0001542898,0.003635484,0.0002086253,0.000164591,0.0001207716,0.001477104,0.0002721755,0.9878188,0.003481688,0.001811501,0.0002849757],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991853,0.0003574727,0.000800444,0.006740669,0.00004013502,0.00006844151,0.000009174179,0.00001782071,0.0001128158],"genre_scores_gemma":[0.9926295,0.0003183588,0.003662412,0.002338973,0.0005123929,0.000004873708,0.000003180765,0.00001960813,0.0005106857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004401696,"threshold_uncertainty_score":0.5513026,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01207551253643506,"score_gpt":0.2589799369595038,"score_spread":0.2469044244230688,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}