{"id":"W2082902184","doi":"10.1021/np8008144","title":"Isolation, Biomimetic Synthesis, and Cytotoxic Activity of Bis(pseudopterane) Amines","year":2009,"lang":"en","type":"article","venue":"Journal of Natural Products","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Prince Edward Island","funders":"University of Prince Edward Island","keywords":"Gorgonian; HeLa; Diterpene; Dichloromethane; Amine gas treating; Chemistry; Stereochemistry; Mass spectrometry; Coral; Combinatorial chemistry; Biology; Organic chemistry; Biochemistry; Chromatography; Cell; Solvent; Ecology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004824009,0.0001895593,0.0004420937,0.00009676447,0.00004375646,0.00002640548,0.0002308059,0.0001160655,0.0001134158],"category_scores_gemma":[0.003406019,0.0001496511,0.00009215032,0.0002421383,0.00009435287,0.0002169509,0.00003124203,0.000347521,8.481845e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005805324,"about_ca_system_score_gemma":0.00008297116,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002039265,"about_ca_topic_score_gemma":1.19743e-7,"domain_scores_codex":[0.998725,0.00005545535,0.0004930787,0.0002200535,0.0003253361,0.0001810574],"domain_scores_gemma":[0.9982189,0.0003531218,0.0006952551,0.0003080315,0.0003460572,0.00007863198],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001515903,0.0001077076,0.0002367664,0.0001660009,0.00005151779,0.00001151553,0.00006820566,8.732393e-7,0.9748076,0.000004829459,0.0001520908,0.02424129],"study_design_scores_gemma":[0.0003575944,0.00004626607,0.004078081,0.0001780371,0.00008616428,0.0007244224,0.00002902352,0.00005086713,0.993856,0.0001471962,0.0002960736,0.0001502337],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944436,0.002282686,0.00004517516,0.002519148,0.0001979814,0.0000418173,0.000003836911,0.00001575531,0.0004500338],"genre_scores_gemma":[0.9895133,0.0001234931,0.009510037,0.00001887677,0.0005100568,3.528012e-7,4.685397e-7,0.00001369941,0.0003097632],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02409106,"threshold_uncertainty_score":0.6102596,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01429112913972349,"score_gpt":0.2667109644037614,"score_spread":0.2524198352640379,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}