{"id":"W2083135806","doi":"10.1021/jp026046r","title":"Charge Trapping at Chemically Modified Si(111) Surfaces Studied by Optical Second Harmonic Generation","year":2002,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Monolayer; Disilane; Photoexcitation; Silicon; Photochemistry; Silane; Analytical Chemistry (journal); Atomic physics; Organic chemistry; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001623155,0.0002416409,0.0004114041,0.000006992579,0.000238734,0.00003366877,0.0003141385,0.00004817205,0.001340999],"category_scores_gemma":[0.00001753935,0.0001612823,0.0002407953,0.0001047958,0.0001675828,0.0001028777,0.00009396634,0.0004786708,0.000026279],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008113431,"about_ca_system_score_gemma":0.00001188952,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002594973,"about_ca_topic_score_gemma":1.268003e-7,"domain_scores_codex":[0.9987146,0.00002943662,0.0003919814,0.000176053,0.0003356338,0.0003522957],"domain_scores_gemma":[0.9991044,0.0001990706,0.0002892015,0.0001731751,0.00009459231,0.0001395285],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008094074,0.0003444251,0.00003215605,0.00002319713,0.0002305923,0.00000102236,0.0003528951,0.00002412699,0.9865241,0.0001183412,0.01215514,0.0001130413],"study_design_scores_gemma":[0.000891973,0.00006533511,0.000009567679,0.00001931561,0.0001117273,0.00000467519,0.00008533071,0.006698893,0.9907454,0.0004115067,0.00076898,0.0001872638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9896129,0.0006728492,0.0001382852,0.00085576,0.00003727239,0.00007044398,0.00002659907,0.00001246999,0.008573471],"genre_scores_gemma":[0.997586,0.0000385297,0.0000173695,0.00004513942,0.001287333,0.000005302784,0.00001084734,0.00001760927,0.0009919225],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01138616,"threshold_uncertainty_score":0.9995719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02225141002470928,"score_gpt":0.2415651771125696,"score_spread":0.2193137670878603,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}