{"id":"W2083381466","doi":"10.1139/v01-060","title":"2000 Alfred Bader Award LectureIn the footsteps of Pasteur: asymmetric induction in the photochemistry of crystalline ammonium carboxylate salts","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Counterion; Chemistry; Carboxylate; Ionic bonding; Mechanistic organic photochemistry; Ammonium; Asymmetric induction; Ion; Reactivity (psychology); Optically active; Salt (chemistry); Organic synthesis; Photochemistry; Organic chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002328056,0.0007673432,0.0003769062,0.0009725782,0.0009380436,0.001959795,0.0006955598,0.002211653,0.02565333],"category_scores_gemma":[0.001443353,0.0002356237,0.000324649,0.0003929845,0.0007862201,0.001425958,0.001052573,0.002923569,0.01295969],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003047929,"about_ca_system_score_gemma":0.002207686,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002491496,"about_ca_topic_score_gemma":0.005152439,"domain_scores_codex":[0.999145,0.0000902153,0.000032308,0.0001385191,0.000441004,0.0001528528],"domain_scores_gemma":[0.998854,0.0001112361,0.00004514087,0.00003576854,0.0005069252,0.0004469893],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00031131,0.0001797146,0.0004230092,0.0001733397,0.0000182416,0.0002504798,0.0001244887,0.0002348126,0.007788968,0.02138699,0.7194529,0.2496557],"study_design_scores_gemma":[0.00002999717,0.0001420304,0.0005695609,0.00006544583,0.000008560352,0.0002250511,0.00005441247,0.0002527177,0.006176046,0.002597375,0.9898648,0.00001399862],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"commentary","genre_gemma":"other","genre_scores_codex":[0.01684478,0.1973339,0.01359619,0.3719498,0.1171669,0.000292051,0.0006085948,0.0005628893,0.281645],"genre_scores_gemma":[0.0540022,0.08834194,0.005796301,0.01759666,0.02059131,0.00005939724,0.0003874158,0.0001890726,0.8130357],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.02565333,"threshold_uncertainty_score":0.08581895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01013580578670193,"score_gpt":0.2074114767882295,"score_spread":0.1972756710015275,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}