{"id":"W2083757138","doi":"10.1139/v01-196","title":"Mechanistic studies of photohydration of <i>m</i>-hydroxy-1,1-diaryl alkenes","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Flash photolysis; Photochemistry; Protonation; Intramolecular force; Markovnikov's rule; Moiety; Excited state; Alkene; Carbocation; Stereochemistry; Organic chemistry; Reaction rate constant","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001548671,0.0002171742,0.0005644703,0.00005781731,0.00009413242,0.00001070457,0.0003543005,0.0001440041,0.001419215],"category_scores_gemma":[0.000287997,0.0002151642,0.0002160981,0.0001694978,0.0002904496,0.00009414212,0.00001225176,0.0002751198,0.000001546815],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001290749,"about_ca_system_score_gemma":0.0003057039,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002088247,"about_ca_topic_score_gemma":0.0002902971,"domain_scores_codex":[0.9985033,0.000009753139,0.0007468539,0.0001563502,0.0002567694,0.0003270072],"domain_scores_gemma":[0.9984557,0.0001012978,0.0004421708,0.0002458139,0.0004493802,0.0003056203],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002191664,0.00004086354,0.0003218843,0.001016886,0.0003553098,0.00005765934,0.000943904,0.00002916603,0.9955065,0.00001251963,0.001384965,0.0003083732],"study_design_scores_gemma":[0.0004884704,0.00003579974,0.000008968337,0.0003398948,0.0001190905,0.000153476,0.0008841763,0.00004298725,0.9958864,0.00053189,0.001334811,0.0001740404],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9741255,0.01203745,0.00003760543,0.0001641932,0.00009417655,0.00003291092,0.00008375054,0.000007581186,0.01341683],"genre_scores_gemma":[0.9984377,0.0006935931,0.00005883328,0.00002228061,0.000120106,0.000004740515,0.000005895841,0.00001857558,0.0006382629],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02431221,"threshold_uncertainty_score":0.9994936,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02277475642339646,"score_gpt":0.2259141227408651,"score_spread":0.2031393663174686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}