{"id":"W2083928006","doi":"10.1021/om800368d","title":"Synthesis and Structure of N-Heterocyclic Carbene Complexes of Germanium(II)","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":84,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Carbene; Substituent; Aryl; Alkyl; Intermolecular force; Germanium; Stereochemistry; NMR spectra database; Proton NMR; Carbon-13 NMR; Spectral line; Medicinal chemistry; Crystallography; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004067043,0.000284041,0.0006871222,0.0001516725,0.0001611758,0.00001348244,0.0003550444,0.0001651842,0.009698058],"category_scores_gemma":[0.00008507124,0.0002720472,0.000132608,0.0003142855,0.0003179053,0.0001351648,0.0002239834,0.0001259343,0.00000373406],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003137361,"about_ca_system_score_gemma":0.00003504575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002565317,"about_ca_topic_score_gemma":0.000006158979,"domain_scores_codex":[0.9984254,0.000021628,0.0006401255,0.0003404465,0.000333961,0.0002384408],"domain_scores_gemma":[0.9986123,0.0001805142,0.0004362414,0.0005251304,0.0001346859,0.0001111715],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001649904,0.0001486637,0.00791533,0.0001918541,0.0001669373,0.000002872745,0.0004594685,0.00000170383,0.9896335,0.0005507463,0.00001423878,0.0008981902],"study_design_scores_gemma":[0.0002492251,0.00002774288,0.03016592,0.00003992305,0.0001000346,0.00008977519,0.00009129935,0.0000216771,0.9656165,0.00005870645,0.00328095,0.0002582913],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968734,0.0002996507,0.00003795186,0.00006599852,0.00005236933,0.00005300989,0.0002358279,0.00004758617,0.002334144],"genre_scores_gemma":[0.9982949,0.0004220403,0.0004401734,0.00003022357,0.00008639379,0.000002889745,0.00004436387,0.00005705863,0.0006219851],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02401704,"threshold_uncertainty_score":0.9999732,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01649850692412984,"score_gpt":0.2090107778610934,"score_spread":0.1925122709369635,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}