{"id":"W2084183082","doi":"10.1002/elps.200390047","title":"Influence of methanol as a buffer additive on the mobilities of organic cations in capillary electrophoresis","year":2003,"lang":"en","type":"article","venue":"Electrophoresis","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Ionic strength; Solvent; Dielectric; Ion; Methanol; Ionic bonding; Acetonitrile; Electrophoresis; Analytical Chemistry (journal); Capillary electrophoresis; Solvent effects; Inorganic chemistry; Aqueous solution; Physical chemistry; Organic chemistry; Materials science; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002969692,0.0003159864,0.0004463276,0.0003334079,0.00009859234,0.00001202152,0.0004106216,0.0001518918,0.0005169143],"category_scores_gemma":[0.0003465787,0.0002621804,0.0001400503,0.001546065,0.000195073,0.00006365685,0.00002107918,0.0003674051,0.0000417002],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000230069,"about_ca_system_score_gemma":0.000243637,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000139355,"about_ca_topic_score_gemma":0.00007156659,"domain_scores_codex":[0.9979613,0.000218449,0.0006026645,0.0003262593,0.0003471699,0.000544182],"domain_scores_gemma":[0.9983438,0.0005568389,0.0001207715,0.0007168418,0.0001891388,0.00007264393],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003397222,0.0001010727,0.0002013045,0.00003749333,0.0001221431,0.000002307461,0.0004878418,0.0003710045,0.9644276,0.02623154,0.007903833,0.00007986113],"study_design_scores_gemma":[0.0001985004,0.0002696468,0.003882116,0.00003922269,0.00004812566,0.00001126419,0.0002501357,0.00002553709,0.986269,0.003747517,0.005013408,0.0002455439],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9748874,0.02102944,0.00008303302,0.0001027749,0.0000181604,0.000559037,0.00002923737,0.00006097416,0.003229979],"genre_scores_gemma":[0.9370696,0.06226907,0.00003363768,0.00008936342,0.00001572509,0.0003094998,0.00001215607,0.00006088009,0.0001400915],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04123964,"threshold_uncertainty_score":0.999983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004126858482771546,"score_gpt":0.1918398359555398,"score_spread":0.1877129774727683,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}