{"id":"W2084406252","doi":"10.1002/chin.200528232","title":"Allylic Substitution Reactions","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Allylic rearrangement; Substitution (logic); Substitution reaction; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003128206,0.00110915,0.0005171904,0.000872691,0.0006666346,0.000451078,0.000704263,0.0005728039,0.03232602],"category_scores_gemma":[0.0004541276,0.0003032023,0.0003916299,0.0009656551,0.0003763396,0.0007306875,0.0009588667,0.001655779,0.01865378],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005261329,"about_ca_system_score_gemma":0.0006573456,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004039328,"about_ca_topic_score_gemma":0.0008978175,"domain_scores_codex":[0.9995986,0.00005856095,0.00002310534,0.00009304947,0.0001004016,0.0001262411],"domain_scores_gemma":[0.9998661,0.0000192516,0.0000131885,0.00004287143,0.00003353472,0.00002502668],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006834049,0.0003042124,0.0004473718,0.001560536,0.0001087913,0.0008330178,0.0003995672,0.002023231,0.6755046,0.08068396,0.03678003,0.2006713],"study_design_scores_gemma":[0.00004522721,0.0004093171,0.0002600857,0.00005525407,0.00003619347,0.0005710542,0.0000376573,0.001159404,0.8091664,0.004658134,0.1835571,0.00004414339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2231727,0.01800491,0.2663724,0.002096746,0.00510645,0.001047304,0.006227076,0.006467896,0.4715045],"genre_scores_gemma":[0.8031381,0.01357775,0.04502788,0.0009919658,0.000328654,0.0005139943,0.003893022,0.0006552393,0.1318734],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.03232602,"threshold_uncertainty_score":0.1081413,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008206958422142389,"score_gpt":0.2310571086069197,"score_spread":0.2228501501847773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}