{"id":"W2084406252","doi":"10.1002/chin.200528232","title":"Allylic Substitution Reactions","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Allylic rearrangement; Substitution (logic); Substitution reaction; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005096676,0.00007080862,0.00006322466,0.00001461605,0.00004712662,0.00001255239,0.00008365153,0.0000807795,0.0002086828],"category_scores_gemma":[0.00005648495,0.00006381015,0.00009311186,0.00005735752,0.00003381857,0.000004307976,0.00003012298,0.0000392918,0.00008935355],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001989644,"about_ca_system_score_gemma":0.0000172505,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006085729,"about_ca_topic_score_gemma":0.00001063044,"domain_scores_codex":[0.9995621,1.927577e-7,0.0001262546,0.0001240252,0.00006485364,0.000122585],"domain_scores_gemma":[0.9996893,0.000003993897,0.00003716179,0.0001824267,0.00002866854,0.00005842272],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007723569,0.00002955383,0.00008297282,0.000005060062,0.00002740557,1.618377e-7,0.000008129036,0.000004352994,0.8765993,0.0001711827,0.008416953,0.1146473],"study_design_scores_gemma":[0.00005325002,0.00000410821,0.00008337212,0.00000210812,0.000007322928,0.00000313752,0.000006385329,0.00001514644,0.538345,0.00000685417,0.4614211,0.00005222406],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4632205,0.0003515265,0.00008252452,0.000590659,0.00003993553,0.00006050828,0.000006855231,0.0000329242,0.5356146],"genre_scores_gemma":[0.9857622,0.0001278026,0.0001735552,0.0001974746,0.0003810791,0.000009238269,0.000108439,0.000005814801,0.01323435],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5225418,"threshold_uncertainty_score":0.2602102,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008206958422142389,"score_gpt":0.2310571086069197,"score_spread":0.2228501501847773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}