{"id":"W2084538827","doi":"10.1373/clinchem.2005.051847","title":"Characterization of Intact Hemoglobin and Oxaliplatin Interaction by Nanoelectrospray Ionization Tandem Mass Spectrometry","year":2005,"lang":"en","type":"article","venue":"Clinical Chemistry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Health","keywords":"Oxaliplatin; Chemistry; Adduct; Tandem mass spectrometry; Hemoglobin; Electrospray ionization; Mass spectrometry; Chromatography; Colorectal cancer; Biochemistry; Cancer; Internal medicine; Medicine; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002380176,0.0002239077,0.0001761722,0.0004284404,0.0001103937,0.0001846961,0.0001972204,0.0002642242,0.0004991146],"category_scores_gemma":[0.0003844533,0.00007639193,0.00008543656,0.0002364965,0.0001607332,0.0001375581,0.000131223,0.0002767559,0.0001397746],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002539822,"about_ca_system_score_gemma":0.0001946403,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006503949,"about_ca_topic_score_gemma":0.0007418784,"domain_scores_codex":[0.9998048,0.00003002255,0.00001241323,0.00005127975,0.00008242871,0.00001908088],"domain_scores_gemma":[0.9998198,0.00003961752,0.00005510313,0.000008392562,0.00005594612,0.00002126345],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007471751,0.00002503871,0.002340889,0.00003289372,0.00001278223,0.00004726115,0.00001749291,0.0001275362,0.9922101,0.00005707947,0.00005188458,0.005002221],"study_design_scores_gemma":[0.00001201781,0.0002343481,0.02145289,0.00000557564,0.00002132878,0.0004720935,0.00001851246,0.003315764,0.9727724,0.00009683801,0.001591134,0.000007101017],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9496055,0.004062444,0.044097,0.0001464524,0.00002814351,0.00008352296,0.0005045464,0.0001887995,0.00128365],"genre_scores_gemma":[0.9596789,0.001577752,0.03658759,0.0001698488,0.00001866849,0.00007299556,0.0006586799,0.00002575148,0.001209855],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006503949,"threshold_uncertainty_score":0.001842737,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01334780023208951,"score_gpt":0.2997961502809279,"score_spread":0.2864483500488384,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}