{"id":"W2084701126","doi":"10.1039/c5dt00646e","title":"Synthesis and characterization of mixed-valence manganese fluorophosphate and analogues with clathrate-like structures: Mn<sup>III</sup><sub>6</sub>F<sub>12</sub>(PO<sub>3</sub>(OH))<sub>8</sub>[Na<sub>8</sub>(K<sub>x</sub>(H<sub>3</sub>O)<sub>4−x</sub>(H<sub>2</sub>O)<sub>2</sub>)M<sup>IV</sup>(OH)<sub>6</sub>] (M<sup>IV</sup> = Mn, Ti, Ge)","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Chemical Synthesis and Characterization","field":"Environmental Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saskatoon Medical Imaging; University of Saskatchewan","funders":"National Natural Science Foundation of China; Fundamental Research Funds for the Central Universities; National Science Foundation","keywords":"Manganese; Valence (chemistry); Clathrate hydrate; Chemistry; Characterization (materials science); Crystallography; Materials science; Hydrate; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009309487,0.0001756405,0.0001120731,0.00009862729,0.0001008004,0.0001927136,0.0002309231,0.000204216,0.0004646188],"category_scores_gemma":[0.0002116735,0.00008972391,0.0000863462,0.0001185188,0.000151608,0.0001679688,0.0001417313,0.0001511287,0.0001359715],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001775786,"about_ca_system_score_gemma":0.0001657014,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001283009,"about_ca_topic_score_gemma":0.001751324,"domain_scores_codex":[0.999935,0.000005170649,0.000004516506,0.00002117641,0.000025704,0.000008391752],"domain_scores_gemma":[0.9999217,0.000008128586,0.00002486764,0.000008384864,0.00002169298,0.00001523533],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004785238,0.000006050109,0.0002831654,0.00004320481,0.000002848473,0.00003347734,0.00001319314,0.00008152542,0.9980488,0.00004371022,0.00002083234,0.00137536],"study_design_scores_gemma":[0.000007211739,0.0001369876,0.002336506,0.000003760912,0.00001289861,0.0003344119,0.00002759153,0.000643557,0.9944607,0.00001521313,0.002016579,0.000004569848],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948524,0.0003558054,0.003601615,0.00002398957,0.000007204142,0.0000270081,0.000317683,0.00004617764,0.0007680799],"genre_scores_gemma":[0.9916759,0.0003007133,0.006445177,0.00001013736,0.000003035963,0.00002327715,0.0003625787,0.00001769352,0.001161449],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001283009,"threshold_uncertainty_score":0.002551019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009248546562053645,"score_gpt":0.1914381140132332,"score_spread":0.1821895674511796,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}