{"id":"W2084853411","doi":"10.1021/om900778u","title":"Steric and Solvent Effects on the Secondary Kinetic α-Deuterium Isotope Effects in the Reaction of Methyl Iodide with Organoplatinum(II) Complexes: Application of a Second-Order Technique in Measuring the Rates of Rapid Processes","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Steric effects; Kinetic isotope effect; Ligand (biochemistry); Iodide; Solvent; Methyl iodide; Reaction rate constant; Denticity; Medicinal chemistry; Platinum; Deuterium; Solvent effects; Bipyridine; Inorganic chemistry; Photochemistry; Stereochemistry; Organic chemistry; Kinetics; Catalysis; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005510592,0.0002029272,0.0003287458,0.00006837096,0.00008118545,0.00002044706,0.0002842395,0.00007902586,0.00004108893],"category_scores_gemma":[0.0001572456,0.0001126201,0.00002935787,0.000754267,0.0001253588,0.0001088953,0.00003470701,0.0003039881,1.849854e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000363583,"about_ca_system_score_gemma":0.00007788527,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001570156,"about_ca_topic_score_gemma":0.00002476876,"domain_scores_codex":[0.9988983,0.0001027665,0.0003736973,0.0002368691,0.0002296855,0.000158658],"domain_scores_gemma":[0.9983361,0.0007562447,0.0004381762,0.0003451822,0.000106638,0.0000176704],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000115485,0.0001752811,0.0007815802,0.002553817,0.00003812599,0.000001134298,0.001755548,0.00001058523,0.9851922,0.00003725114,0.000002417363,0.009336507],"study_design_scores_gemma":[0.0005052527,0.0002129618,0.009688244,0.000431037,0.00004408729,0.00001331529,0.0005021704,0.00003520244,0.9879354,0.0003457456,0.0001673308,0.0001192736],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969883,0.0005426971,0.0004547194,0.0002124195,0.000005960903,0.0006217454,0.000007424645,0.00001137092,0.00115534],"genre_scores_gemma":[0.999316,0.00005921557,0.0003261551,0.0000774978,0.00002205031,0.0001498287,0.00001607864,0.00001626325,0.00001695423],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009217233,"threshold_uncertainty_score":0.4592513,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01133499434681971,"score_gpt":0.2345064350834744,"score_spread":0.2231714407366547,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}