{"id":"W2084853411","doi":"10.1021/om900778u","title":"Steric and Solvent Effects on the Secondary Kinetic α-Deuterium Isotope Effects in the Reaction of Methyl Iodide with Organoplatinum(II) Complexes: Application of a Second-Order Technique in Measuring the Rates of Rapid Processes","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Steric effects; Kinetic isotope effect; Ligand (biochemistry); Iodide; Solvent; Methyl iodide; Reaction rate constant; Denticity; Medicinal chemistry; Platinum; Deuterium; Solvent effects; Bipyridine; Inorganic chemistry; Photochemistry; Stereochemistry; Organic chemistry; Kinetics; Catalysis; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007781423,0.0006816052,0.0004503491,0.0002646942,0.0002103948,0.0005067328,0.0003705185,0.0003741324,0.0009666829],"category_scores_gemma":[0.001037226,0.0004328701,0.0003775616,0.0002849265,0.0005771671,0.0005082822,0.000380072,0.0006533039,0.00027312],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005483135,"about_ca_system_score_gemma":0.0003446567,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001228386,"about_ca_topic_score_gemma":0.001579868,"domain_scores_codex":[0.999665,0.00009044691,0.00002210188,0.00007405909,0.00008533105,0.00006304939],"domain_scores_gemma":[0.9994412,0.0002779913,0.00011355,0.00004581372,0.00008200833,0.00003944662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001823423,0.000007556883,0.0003883567,0.00006675508,0.00001323508,0.00003584375,0.00007715117,0.0001633332,0.9979032,0.00006209247,0.00001231117,0.001087723],"study_design_scores_gemma":[0.000006133171,0.00007920706,0.0005858414,0.000001814392,0.000009356208,0.0000333633,0.00001458781,0.0007007967,0.9983287,0.00001091896,0.0002231845,0.000005885212],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899796,0.001601522,0.006724285,0.00006435987,0.00002642725,0.00003467646,0.0001764358,0.00008864086,0.001304045],"genre_scores_gemma":[0.9928814,0.001004605,0.004138749,0.00001907086,0.000007256281,0.00002764229,0.0001520505,0.00003781476,0.001731373],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001228386,"threshold_uncertainty_score":0.004115224,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01133499434681971,"score_gpt":0.2345064350834744,"score_spread":0.2231714407366547,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}