{"id":"W2085082127","doi":"10.1016/j.ccr.2014.09.003","title":"Covalent multi-component systems of polyoxometalates and metal complexes: Toward multi-functional organic–inorganic hybrids in molecular and material sciences","year":2014,"lang":"en","type":"article","venue":"Coordination Chemistry Reviews","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":172,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Université Pierre et Marie Curie; Université de Montréal; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Supramolecular chemistry; Hybrid material; Catalysis; Component (thermodynamics); Coordination complex; Nanotechnology; Covalent bond; Transition metal; Organic component; Rational design; Polyoxometalate; Combinatorial chemistry; Metal; Organic chemistry; Molecule; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001279037,0.0002214681,0.0005772833,0.00007725025,0.0001235733,0.000109425,0.0002138383,0.00006734685,0.0002984209],"category_scores_gemma":[0.0002677443,0.0001874591,0.0000623829,0.0002817115,0.0003343036,0.0001592235,0.0001295445,0.00006572896,0.00001886202],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000435308,"about_ca_system_score_gemma":0.00003186177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004892986,"about_ca_topic_score_gemma":0.000001761816,"domain_scores_codex":[0.9982237,0.0001490946,0.0007005499,0.0004784588,0.0002295252,0.0002187307],"domain_scores_gemma":[0.999128,0.00009688344,0.0003767136,0.0002267406,0.0000772453,0.00009435852],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000003466596,0.000106,0.0008447341,0.000398912,0.000007447134,2.938013e-7,0.00003081781,0.00001238097,0.9979112,0.0002942485,0.00001798445,0.0003725404],"study_design_scores_gemma":[0.0005249484,0.00002144775,0.004559899,0.0001801575,0.00005063886,0.0000340636,0.00006123186,0.003571338,0.9888998,0.00003426479,0.001831172,0.0002310162],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878675,0.005826338,0.005473102,0.0001510596,0.0001255209,0.0004224334,0.00005034635,0.00003089377,0.00005286041],"genre_scores_gemma":[0.9968307,0.0004652139,0.002410254,0.00002106556,0.0000391327,0.00009187177,0.00002934975,0.00001451155,0.00009789786],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009011352,"threshold_uncertainty_score":0.764436,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04548943928164308,"score_gpt":0.2750501861726934,"score_spread":0.2295607468910503,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}