{"id":"W2085187921","doi":"10.1016/j.aca.2005.04.075","title":"The leaching of V(V) with PO43− in the speciation analysis of soil","year":2005,"lang":"en","type":"article","venue":"Analytica Chimica Acta","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"National Research Council Canada; National Research Foundation","keywords":"Chemistry; Vanadium; Leaching (pedology); Reagent; Soil test; Phosphate; Contamination; Environmental chemistry; Soil water; Soil science; Inorganic chemistry; Environmental science","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006010772,0.0002762853,0.0002412346,0.0003060011,0.0003003814,0.0009497644,0.0004495774,0.0007653036,0.0003600628],"category_scores_gemma":[0.0007868475,0.0002940054,0.0002829533,0.0003028157,0.0002508799,0.0004509221,0.0003445822,0.0003307425,0.0002563222],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003295304,"about_ca_system_score_gemma":0.0004382753,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002441286,"about_ca_topic_score_gemma":0.003373278,"domain_scores_codex":[0.9996002,0.0001219468,0.00002094133,0.00009075693,0.00009280848,0.00007331504],"domain_scores_gemma":[0.9998769,0.00003672732,0.00001818113,0.00001241242,0.00003856857,0.00001713131],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005378657,0.00003294324,0.004190259,0.0001056542,0.00003812979,0.00009612522,0.0001075295,0.0006082789,0.9809493,0.0001853868,0.00005273475,0.01309565],"study_design_scores_gemma":[0.00001177632,0.0003060295,0.005259759,0.00001278469,0.00003854803,0.0002681486,0.0001522117,0.003537948,0.9883094,0.0001521339,0.001942232,0.000009093506],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9856477,0.001643291,0.01120041,0.00007894066,0.00002624259,0.00002524416,0.0001269307,0.00004129693,0.001209992],"genre_scores_gemma":[0.9886206,0.0007633229,0.007428575,0.00005136076,0.000006188678,0.00001891788,0.0001604484,0.00002151213,0.002929022],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002441286,"threshold_uncertainty_score":0.004854143,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009372013043710077,"score_gpt":0.2345182864473289,"score_spread":0.2251462734036188,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}