{"id":"W2085198678","doi":"10.1039/c1cc13117f","title":"Redox control of a polymerization catalyst by changing the oxidation state of the metal center","year":2011,"lang":"en","type":"article","venue":"Chemical Communications","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":153,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Polymerization; Cerium; Alkoxide; Redox; Chemistry; Polymer chemistry; Catalysis; Reagent; Oxidation state; Metal; Ligand (biochemistry); Lactide; Schiff base; Photochemistry; Inorganic chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002628045,0.0003383831,0.0002175345,0.0001793165,0.0001205711,0.0003824955,0.0003879496,0.0003429189,0.0006288155],"category_scores_gemma":[0.0004598963,0.0001736087,0.0001563637,0.0001204306,0.0002648399,0.0003366414,0.0001857094,0.0005347571,0.0001934964],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002381731,"about_ca_system_score_gemma":0.0002006101,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002336051,"about_ca_topic_score_gemma":0.0003051973,"domain_scores_codex":[0.9998701,0.0000185615,0.00001330712,0.00004008332,0.00002844025,0.00002941965],"domain_scores_gemma":[0.9998527,0.00004581693,0.00003659431,0.00002027894,0.00002388365,0.00002082067],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007715635,0.00001438859,0.00004905614,0.00003102971,0.000003236801,0.00002740131,0.00001979577,0.00007776335,0.997308,0.0002419517,0.00002728116,0.002122867],"study_design_scores_gemma":[0.000007612264,0.00003988613,0.00007170772,0.000001217314,0.000003479098,0.00002660466,0.000002786773,0.0004566424,0.9989549,0.00002499152,0.0004081688,0.000002039199],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908156,0.0009157312,0.006153043,0.0001407586,0.00005094826,0.00002698075,0.00005950783,0.0001330849,0.001704302],"genre_scores_gemma":[0.9950885,0.0003802487,0.003322701,0.00002708264,0.000009429481,0.000009669256,0.00005382196,0.00002967957,0.001078925],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006288155,"threshold_uncertainty_score":0.002103627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03107021413657845,"score_gpt":0.2221564638725599,"score_spread":0.1910862497359815,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}