{"id":"W2085475641","doi":"10.1021/ol016245d","title":"Stereoselective <i>C</i>-Glycoside Formation by a Rhodium(I)-Catalyzed 1,4-Addition of Arylboronic Acids to Acetylated Enones Derived from Glycals","year":2001,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":80,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Rhodium; Stereoselectivity; Acetylation; Catalysis; Glycoside; Organic chemistry; Stereochemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008520929,0.0002982629,0.000387291,0.00005666438,0.0001004494,0.00004647667,0.0003066418,0.0001930349,0.003520434],"category_scores_gemma":[0.0001209448,0.000317488,0.0001243532,0.0003545245,0.00006047656,0.0003271213,0.00007447343,0.0001961982,0.0001076143],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003434824,"about_ca_system_score_gemma":0.00004375141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001607168,"about_ca_topic_score_gemma":0.00003999334,"domain_scores_codex":[0.9983926,0.00003765572,0.0004824629,0.0004199113,0.0002814468,0.0003859404],"domain_scores_gemma":[0.998875,0.00018493,0.0002450038,0.0004718355,0.0000768777,0.0001464161],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002354637,0.00007953889,0.0001674699,0.00004482745,0.0001197664,0.00001187661,0.0009514817,0.000005628557,0.9942257,7.812734e-7,0.003227022,0.0009304004],"study_design_scores_gemma":[0.000925549,0.00001453637,0.0001622964,0.0001001333,0.00009372355,0.00002070543,0.0003029888,0.00006074306,0.9970154,0.00003176492,0.0009322978,0.0003398178],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947914,0.00008538923,0.002308793,0.001629791,0.0000545109,0.0001326992,0.0003542282,0.0001390234,0.0005041969],"genre_scores_gemma":[0.997717,0.00005924633,0.0001729893,0.000690683,0.0001376494,0.00004374211,0.001057164,0.00004980194,0.00007174924],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00341282,"threshold_uncertainty_score":0.9999277,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007394664279978711,"score_gpt":0.1976282597574761,"score_spread":0.1902335954774974,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}