{"id":"W2085522892","doi":"10.1016/s1381-1169(03)00303-0","title":"Intermediates of cobalt-catalysed PTC carbonylation of benzyl halides","year":2003,"lang":"en","type":"article","venue":"Journal of Molecular Catalysis A Chemical","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"","keywords":"Carbonylation; Halide; Cobalt; Chemistry; Catalysis; Medicinal chemistry; Organic chemistry; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003309235,0.0001777815,0.0005773841,0.0001274747,0.00001562181,0.00001307461,0.0003244022,0.0001719135,0.0004035846],"category_scores_gemma":[0.001229692,0.000169142,0.000525871,0.0003628735,0.0001412573,0.00009935204,0.00004973737,0.0002472411,0.000001285825],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008136083,"about_ca_system_score_gemma":0.0001277648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008530782,"about_ca_topic_score_gemma":8.990502e-7,"domain_scores_codex":[0.9980662,0.00002763045,0.001050244,0.0001705926,0.0005272052,0.0001581677],"domain_scores_gemma":[0.9977939,0.0001311184,0.001125761,0.0003298047,0.0004902018,0.0001292821],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004365927,0.000234965,0.002432132,0.0001946957,0.0003708194,0.00001971462,0.0001399928,0.00004638796,0.9959824,0.0001115328,0.00003600498,0.0003876879],"study_design_scores_gemma":[0.0007002349,0.00001801503,0.00004980443,0.00008372449,0.0003939595,0.00007577144,0.0001698345,0.00005299224,0.9976798,0.0003030772,0.0003340847,0.0001387288],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964043,0.0008540241,0.0004919105,0.00006322462,0.00003524357,0.00002171448,0.00001481861,0.000006394946,0.002108344],"genre_scores_gemma":[0.9988481,0.00003538885,0.0009273806,0.00001270363,0.00004913269,0.000001534384,0.00005905202,0.00001959444,0.00004712122],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002443767,"threshold_uncertainty_score":0.689741,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006611041069616693,"score_gpt":0.2219906299048617,"score_spread":0.2153795888352451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}