{"id":"W2085860246","doi":"10.1021/ja001445q","title":"Carbon−Carbon Double Bond Formation Reactions of the Unique Spirocyclic Aluminum Bis(iminophosphorano) Methandiide Complex:  Insertion of Heteroallenes into Aluminum−Carbon Bonds","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Citation; Altmetrics; Computer science; Aluminium; Carbon fibers; Library science; Chemistry; World Wide Web; Nanotechnology; Information retrieval; Materials science; Algorithm; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003917497,0.0002838997,0.00080372,0.00004344735,0.000107021,0.00002251831,0.0008412611,0.0001368727,0.0003031974],"category_scores_gemma":[0.00006869841,0.0001864452,0.001094586,0.00073198,0.0006361683,0.0001132467,0.0001720339,0.0004981252,3.29558e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003881268,"about_ca_system_score_gemma":0.0001142546,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001651756,"about_ca_topic_score_gemma":0.00002943907,"domain_scores_codex":[0.9974832,0.0000748488,0.001198176,0.000227637,0.0007306324,0.0002854961],"domain_scores_gemma":[0.9967833,0.0001605994,0.002033376,0.000712053,0.0002002111,0.0001104748],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001745465,0.0002276392,0.001471581,0.0001097568,0.0003234094,3.86921e-7,0.0008060946,0.00005060991,0.9928257,0.000006757986,0.00009963295,0.003903824],"study_design_scores_gemma":[0.0006335421,0.00005582087,0.002664201,0.0001335923,0.0004145719,0.00004466359,0.0009848955,0.0009789153,0.9909105,0.0002371812,0.002739654,0.0002025194],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955813,0.000265444,0.000005391305,0.001115452,0.00005129454,0.00009361617,0.000009515457,0.00001638252,0.00286165],"genre_scores_gemma":[0.9986206,0.0003304484,0.0004791479,0.0001110089,0.0001425536,0.000008987719,0.000005681221,0.00003402346,0.0002675385],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003701304,"threshold_uncertainty_score":0.7603014,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01741616412175944,"score_gpt":0.2445893510865634,"score_spread":0.227173186964804,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}