{"id":"W2086103150","doi":"10.1016/s1044-0305(02)00353-7","title":"Gas-phase fragmentation of the Ag<sup>+</sup>—phenylalanine complex: Cation—π interactions and radical cation formation","year":2002,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Fragmentation (computing); Deuterium; Dissociation (chemistry); Collision-induced dissociation; Ion; Yield (engineering); Phenylalanine; Gas phase; Mass spectrometry; Density functional theory; Tandem mass spectrometry; Analytical Chemistry (journal); Computational chemistry; Atomic physics; Physical chemistry; Chromatography; Amino acid; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002139951,0.0003666006,0.0003401003,0.0002735677,0.0004887184,0.0003165344,0.0005061238,0.0005920742,0.001565967],"category_scores_gemma":[0.0002724015,0.0001233313,0.0001522717,0.0004018275,0.0002455899,0.000273108,0.0001818571,0.0003441353,0.0002720934],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000365578,"about_ca_system_score_gemma":0.0001756926,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001129986,"about_ca_topic_score_gemma":0.0007890633,"domain_scores_codex":[0.9998715,0.00001740594,0.000004880748,0.00003074208,0.00004441127,0.00003103228],"domain_scores_gemma":[0.9998802,0.00004960024,0.00002276248,0.00001027338,0.00002223756,0.00001486889],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006220812,0.00003291962,0.001382817,0.00007760864,0.0000189282,0.0002991893,0.00006851708,0.0002314892,0.9907232,0.0003419665,0.0002842582,0.005917015],"study_design_scores_gemma":[0.00004188884,0.0001883069,0.006111283,0.000005600844,0.00001612292,0.0007711443,0.00003993357,0.002523348,0.9883884,0.000265833,0.001634737,0.00001334895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933134,0.0009117263,0.003924705,0.00008085188,0.00001267825,0.00001937017,0.0003674563,0.00006379182,0.001305916],"genre_scores_gemma":[0.9955472,0.0002942002,0.003027464,0.00003878966,0.000003446957,0.00000970663,0.0004245146,0.00002179795,0.0006329117],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001565967,"threshold_uncertainty_score":0.005238652,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02109712470020048,"score_gpt":0.2953771338419402,"score_spread":0.2742800091417397,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}