{"id":"W2086291299","doi":"10.1021/ic000328t","title":"Preparation and Characterization of Oxorhenium(V) Complexes with 2,2‘-Biimidazole:  The Strong Affinity of Coordinated Biimidazole for Chloride Ions via N−H···Cl<sup>-</sup> Hydrogen Bonding","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Radiopharmaceutical Chemistry and Applications","field":"Medicine","cited_by":71,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Hydrogen bond; Counterion; Crystallography; Acetone; Chelation; Chloride; Crystal structure; Stereochemistry; Ion; Medicinal chemistry; Molecule; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001145952,0.0001794166,0.0003036465,0.00001673096,0.0001491944,0.00001388931,0.0001341724,0.0001160688,0.0003576841],"category_scores_gemma":[0.00003321659,0.0001430607,0.0000599324,0.0002871276,0.0002355468,0.00008389307,0.00002598905,0.0001746495,0.000001837716],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004494083,"about_ca_system_score_gemma":0.00008771075,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008676962,"about_ca_topic_score_gemma":5.495476e-7,"domain_scores_codex":[0.9989545,0.00001112797,0.0003984508,0.0002688656,0.000168192,0.0001988312],"domain_scores_gemma":[0.9991319,0.0001037147,0.0001866965,0.000334989,0.0001294087,0.0001133394],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004873837,0.0001643608,0.001090965,0.000391188,0.00009722178,6.449254e-7,0.0002444651,0.0001633615,0.9969473,0.00004167845,0.00003237883,0.0003390849],"study_design_scores_gemma":[0.001255367,0.0000521832,0.001319589,0.00008344956,0.0002612053,0.00007679935,0.0001103518,0.009229754,0.9865057,0.00003376821,0.0009387254,0.0001330847],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974821,0.00005317942,0.0003967493,0.0005832247,0.000004153262,0.0005139352,0.0001439711,0.00004854891,0.0007741335],"genre_scores_gemma":[0.9986826,0.00003125129,0.00009460132,0.00003775282,0.0001081891,0.00007399876,0.0004465802,0.00002420369,0.0005007872],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01044154,"threshold_uncertainty_score":0.5833846,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01547703589707946,"score_gpt":0.278300995836499,"score_spread":0.2628239599394195,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}