{"id":"W2086342576","doi":"10.1139/v08-028","title":"Correlation of the rates of solvolysis of acetyl chloride and α-substituted derivatives","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Center for Research Resources; American Chemical Society Petroleum Research Fund; National Institutes of Health","keywords":"Solvolysis; Chemistry; Nucleophile; Chloride; Solvent; Kinetic isotope effect; Solvent effects; Chloroacetyl chloride; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Hydrolysis; Catalysis; Deuterium","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008385666,0.0001007964,0.0002788329,0.00003452702,0.00004729757,0.000003661885,0.0002156841,0.0001259078,0.0004057143],"category_scores_gemma":[0.0006699039,0.0000840482,0.0001272317,0.0001638822,0.000340725,0.00007768561,0.00001586659,0.0002301786,1.851874e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008007349,"about_ca_system_score_gemma":0.000701246,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003239941,"about_ca_topic_score_gemma":0.00008497024,"domain_scores_codex":[0.9991041,0.000006082191,0.0004887303,0.00008350197,0.0001956464,0.0001219239],"domain_scores_gemma":[0.9984195,0.0001099036,0.0007623666,0.0001853042,0.000315254,0.000207637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002710626,0.00001285185,0.01109107,0.0001406403,0.00006470788,0.000005797036,0.000356108,0.00006197495,0.9880329,0.00001316019,0.00008367153,0.0001099954],"study_design_scores_gemma":[0.0003695722,0.000005909184,0.001502095,0.0001913788,0.00004006122,0.0001581014,0.0003748143,0.00005654321,0.9968927,0.0001557068,0.0001860502,0.00006708561],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978083,0.0003183263,0.0000902902,0.00008773081,0.00004992314,0.00001694339,0.00002771583,0.000001740762,0.001598968],"genre_scores_gemma":[0.99947,0.00005708988,0.0001419869,0.000007077221,0.00005448536,5.321033e-7,0.000003817451,0.000009406162,0.0002556331],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009588977,"threshold_uncertainty_score":0.4442287,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01439487445832081,"score_gpt":0.2118957901402408,"score_spread":0.19750091568192,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}