{"id":"W2086447961","doi":"10.1139/v05-131","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes. Part IV.<sup>1</sup> Synthesis and characterization of 1-[2-aryl-1-diazenyl]-3-(3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)hexahydropyrimidines and 1-(5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)-5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydropyrimidines from the reaction of diazonium salts with mixtures of formaldehyde and 1,3-diaminopropanes","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Aryl; Molecule; DEPT; Triazene; Methylamine; Stereochemistry; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.002022919,0.001991413,0.003957028,0.0009234036,0.0006335566,0.0002006257,0.0016008,0.001563371,0.0006519266],"category_scores_gemma":[0.002226096,0.001679872,0.0008715003,0.001423467,0.002571245,0.001684097,0.0003864881,0.002028345,0.000002448106],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003914153,"about_ca_system_score_gemma":0.001638394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005818611,"about_ca_topic_score_gemma":0.00057942,"domain_scores_codex":[0.9900317,0.0002379126,0.004562733,0.001704832,0.001725306,0.001737539],"domain_scores_gemma":[0.9856354,0.003507382,0.005468552,0.001873156,0.001541077,0.001974449],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001452438,0.0005028754,0.004593286,0.002105934,0.001509149,0.00007733441,0.003110961,0.0003316522,0.9787483,0.00007541918,0.0004378872,0.007054781],"study_design_scores_gemma":[0.003762557,0.0004319287,0.001837562,0.002291382,0.001903244,0.0006491981,0.002910815,0.001421879,0.9789555,0.0006108143,0.003671328,0.001553786],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.984378,0.01036428,0.00008899969,0.001352812,0.0003028976,0.0007797362,0.001844928,0.00009005873,0.0007982687],"genre_scores_gemma":[0.9886028,0.007657647,0.001360712,0.0001961465,0.00116891,0.00009476913,0.0003879431,0.0003397167,0.0001913936],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005500996,"threshold_uncertainty_score":0.9997328,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00955878031581126,"score_gpt":0.1975517680530559,"score_spread":0.1879929877372447,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}