{"id":"W2086447961","doi":"10.1139/v05-131","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes. Part IV.<sup>1</sup> Synthesis and characterization of 1-[2-aryl-1-diazenyl]-3-(3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)hexahydropyrimidines and 1-(5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydro-1-pyrimidinylmethyl)-5,5-dimethyl-3-[2-aryl-1-diazenyl]hexahydropyrimidines from the reaction of diazonium salts with mixtures of formaldehyde and 1,3-diaminopropanes","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Aryl; Molecule; DEPT; Triazene; Methylamine; Stereochemistry; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006641513,0.0002711733,0.0001510494,0.0001205312,0.0001041585,0.0001770165,0.0002737559,0.0002522849,0.003730953],"category_scores_gemma":[0.0001634259,0.0001277397,0.0001783206,0.0001145181,0.0001646501,0.0001776118,0.0001487857,0.0003491324,0.0008842474],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002676744,"about_ca_system_score_gemma":0.0001469194,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004534058,"about_ca_topic_score_gemma":0.0007527801,"domain_scores_codex":[0.9999222,0.000009983492,0.000005510381,0.00001693649,0.00002165434,0.00002374651],"domain_scores_gemma":[0.9999205,0.00001237138,0.0000284704,0.00001009431,0.00001278825,0.00001575389],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004009676,0.000005927169,0.00004535035,0.00003517847,0.000002072433,0.00003288843,0.000008673468,0.00003951203,0.998724,0.00012391,0.00004551773,0.0008968448],"study_design_scores_gemma":[0.000005864435,0.0001544417,0.0006725189,0.000003483006,0.000006228297,0.0001143559,0.0000113697,0.0001232482,0.9957431,0.0000223536,0.003140448,0.000002683214],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9744,0.003636451,0.008273913,0.000146166,0.000117773,0.00006080681,0.0007143685,0.0003155969,0.01233494],"genre_scores_gemma":[0.9762166,0.001942288,0.006357504,0.0001001699,0.00001724472,0.00008568915,0.0008814252,0.00006628576,0.01433269],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003730953,"threshold_uncertainty_score":0.01248127,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00955878031581126,"score_gpt":0.1975517680530559,"score_spread":0.1879929877372447,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}