{"id":"W2086692218","doi":"10.1021/jo701383d","title":"Study on the Reactivity of Oxabicyclic Alkenes in Ruthenium-Catalyzed [2+2] Cycloadditions","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Cycloaddition; Bicyclic molecule; Substituent; Alkene; Ruthenium; Reactivity (psychology); Alkyne; Medicinal chemistry; Catalysis; Benzene; Ring (chemistry); Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003304976,0.0003743807,0.0003152983,0.0002203167,0.0001533302,0.0003048396,0.0002237107,0.0003036185,0.001217281],"category_scores_gemma":[0.0004195129,0.0001507476,0.0001860444,0.0002355577,0.0001532349,0.0002715424,0.0001063181,0.0002993243,0.0003183311],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001308102,"about_ca_system_score_gemma":0.0001282356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003891056,"about_ca_topic_score_gemma":0.0004604905,"domain_scores_codex":[0.9998268,0.00004612619,0.000008083568,0.000025633,0.00004030883,0.00005298339],"domain_scores_gemma":[0.9997937,0.00009640445,0.00004090642,0.00002074814,0.00002822361,0.0000199826],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002383736,0.00003718719,0.0002835427,0.0000950932,0.00001685286,0.0001600914,0.00005196024,0.0006588195,0.9954476,0.0002518332,0.00003493659,0.002723705],"study_design_scores_gemma":[0.00001198072,0.0003485383,0.001187172,0.000006664056,0.00002367925,0.0002197946,0.00001906841,0.0007299631,0.9960815,0.00003918529,0.001321701,0.00001085633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944559,0.001884282,0.001141245,0.00002400138,0.000009934693,0.00002001027,0.00008062946,0.00001930092,0.002364659],"genre_scores_gemma":[0.9964511,0.001147548,0.0009841743,0.00001391149,0.000005867295,0.00001217414,0.0001349397,0.000008183423,0.001242168],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001217281,"threshold_uncertainty_score":0.004072189,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01971440245640574,"score_gpt":0.2646757367369328,"score_spread":0.2449613342805271,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}