{"id":"W2086692218","doi":"10.1021/jo701383d","title":"Study on the Reactivity of Oxabicyclic Alkenes in Ruthenium-Catalyzed [2+2] Cycloadditions","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Cycloaddition; Bicyclic molecule; Substituent; Alkene; Ruthenium; Reactivity (psychology); Alkyne; Medicinal chemistry; Catalysis; Benzene; Ring (chemistry); Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001557402,0.0001975553,0.0003374491,0.00005196996,0.0001229418,0.00001576834,0.0006960973,0.0001074037,0.001451375],"category_scores_gemma":[0.0008128214,0.0001212811,0.0001598079,0.0004091317,0.0001746955,0.00009091932,0.0001031126,0.0009130797,0.00001534665],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000279582,"about_ca_system_score_gemma":0.0001747293,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004888623,"about_ca_topic_score_gemma":0.00005634301,"domain_scores_codex":[0.9983011,0.00003715031,0.0007587604,0.0001367848,0.000512599,0.0002536129],"domain_scores_gemma":[0.9965185,0.001695485,0.0007869568,0.0007821505,0.0001343702,0.00008253355],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001441743,0.0009401542,0.001396741,0.00002165814,0.0001338715,0.00003067449,0.001241554,0.000004751455,0.9955535,0.000004858833,0.0002191045,0.0003089844],"study_design_scores_gemma":[0.0008124475,0.00002327416,0.008275589,0.00009373244,0.000170746,0.000604499,0.01332529,0.00000198226,0.976113,0.0001741001,0.0002805986,0.0001247742],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909829,0.0000838202,0.00003424199,0.0007080441,0.00005889417,0.00008298892,0.00001974746,0.00001480941,0.008014592],"genre_scores_gemma":[0.9993407,0.00003651145,0.000009305717,0.00001667026,0.0002769225,0.000002347542,0.000004699461,0.0000293112,0.0002835206],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01944051,"threshold_uncertainty_score":0.9994614,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01971440245640574,"score_gpt":0.2646757367369328,"score_spread":0.2449613342805271,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}