{"id":"W2086702797","doi":"10.1021/ol101520q","title":"β-Selective Arabinofuranosylation Using a 2,3-<i>O</i>-Xylylene-Protected Donor","year":2010,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Glycomics Centre; University of Alberta","funders":"","keywords":"Chemistry; Xylylene; Lipoarabinomannan; Stereoselectivity; Glycosylation; Protecting group; Oligosaccharide; Oxocarbenium; Stereochemistry; Fucosylation; Substrate (aquarium); Polysaccharide; Acceptor; Alcohol; Combinatorial chemistry; Fucose; Organic chemistry; Biochemistry; Galactose; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001690345,0.0005291349,0.0003395864,0.0001027176,0.0001863368,0.0002920517,0.0003206735,0.0003055519,0.0009132721],"category_scores_gemma":[0.00008116089,0.0002010218,0.0002071743,0.0001123471,0.0003396623,0.0003665777,0.0002445322,0.00066916,0.0004777903],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002060202,"about_ca_system_score_gemma":0.0002871493,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000312586,"about_ca_topic_score_gemma":0.0003018821,"domain_scores_codex":[0.9999202,0.00001318432,0.000004775536,0.0000205043,0.00001426532,0.0000269688],"domain_scores_gemma":[0.9999408,0.000008261594,0.00001999225,0.000008714448,0.000005909089,0.00001626583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005227623,0.0000308755,0.00008240732,0.00004126798,0.000003725029,0.0001326907,0.00003206382,0.00008604234,0.9948463,0.000474196,0.00005049531,0.004167602],"study_design_scores_gemma":[0.00001032149,0.0001647145,0.0002221249,0.000001413125,0.000005630261,0.0002831645,0.000007832125,0.0001702516,0.997279,0.0000370748,0.001813427,0.000005095941],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9386935,0.00176722,0.04951392,0.0002276605,0.0001094467,0.0001591907,0.0002301031,0.0003202061,0.008978833],"genre_scores_gemma":[0.9789382,0.001254109,0.01711894,0.00007252593,0.00002408086,0.00004762952,0.0001964953,0.00003526116,0.002312718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009132721,"threshold_uncertainty_score":0.003055155,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009272869406944027,"score_gpt":0.2037436704550485,"score_spread":0.1944708010481045,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}