{"id":"W2086717726","doi":"10.1139/v03-205","title":"RZnI vs. R<sub>2</sub>Zn in Pd(0)-catalyzed cross-coupling reactions with thioimidates","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Nucleophile; Reactivity (psychology); Catalysis; Inert; Coupling (piping); Lewis acids and bases; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Metallurgy","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003431423,0.0003068556,0.0004116444,0.0001884207,0.0001645663,0.0001684143,0.0005684622,0.0003275917,0.0003435966],"category_scores_gemma":[0.0004641559,0.0003052726,0.0001619342,0.0003040353,0.0002845156,0.0003148681,0.00001716557,0.0009338796,0.00001104981],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001147548,"about_ca_system_score_gemma":0.002883284,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001764264,"about_ca_topic_score_gemma":0.004262173,"domain_scores_codex":[0.9981027,0.000005534742,0.0007064728,0.0002987368,0.0003071431,0.0005794004],"domain_scores_gemma":[0.9978809,0.0001166546,0.0004745149,0.0004896117,0.0002959892,0.000742337],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007469697,0.00004252798,0.009694808,0.0001474954,0.00005846938,0.000710985,0.0001406211,0.0008144379,0.9879274,0.000007775641,0.0001138079,0.0002670031],"study_design_scores_gemma":[0.0008970363,0.00001301922,0.0008536266,0.0008986903,0.00003339131,0.0007514108,0.000274124,0.000009787309,0.9946959,0.0003774308,0.0008573416,0.0003382399],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947816,0.0002842783,0.00004788474,0.0004486701,0.00004917142,0.00004315706,0.00003756733,0.0000537334,0.004253948],"genre_scores_gemma":[0.9989341,0.00004498857,0.0005108271,0.00006196278,0.0002773432,0.00001215666,0.00002142201,0.00006808984,0.00006904264],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008841182,"threshold_uncertainty_score":0.9999399,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009202264578663575,"score_gpt":0.2261123215099189,"score_spread":0.2169100569312553,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}