{"id":"W2086781393","doi":"10.1039/c4ra01542h","title":"Diastereodivergent total synthesis of mosquito oviposition pheromone","year":2014,"lang":"en","type":"article","venue":"RSC Advances","topic":"Chemistry and Chemical Engineering","field":"Environmental Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Pheromone; Yield (engineering); Diastereomer; Stereochemistry; Chemistry; Total synthesis; Organic chemistry; Biology; Botany; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003499541,0.0000594472,0.00007889325,0.000003218374,0.0000198694,0.000002886979,0.00007371268,0.0000222758,0.0007474088],"category_scores_gemma":[0.00003498692,0.00005476453,0.00002995643,0.00004800329,0.00004635366,0.0001076568,0.00005112348,0.00003029179,0.00004917817],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002466543,"about_ca_system_score_gemma":5.67408e-7,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008593566,"about_ca_topic_score_gemma":0.000001014313,"domain_scores_codex":[0.9995786,0.000005131852,0.0000901818,0.0001161149,0.0001143963,0.00009556458],"domain_scores_gemma":[0.9997831,0.00004360723,0.00003231211,0.00009651326,0.000001832419,0.00004261633],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008692829,0.00003988943,0.001364525,0.00003575284,0.000004158756,5.103323e-7,0.00004451129,0.01055895,0.9482155,0.00002422541,0.00006077836,0.03964253],"study_design_scores_gemma":[0.00005730843,0.00001358718,0.001694635,0.00001951457,0.000007426454,0.000002125177,0.00001763589,0.001449081,0.9948503,0.000148175,0.001659589,0.00008057625],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9832764,0.00008331925,0.001947987,0.00002378785,0.00004846847,0.00002319477,0.000003989376,0.00002171132,0.0145712],"genre_scores_gemma":[0.9987711,0.00002253926,0.001042737,0.000008746647,0.00003774282,0.000006417136,0.000001627982,0.000003869978,0.0001052232],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04663487,"threshold_uncertainty_score":0.8183603,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003510303663375553,"score_gpt":0.1870567262233597,"score_spread":0.1835464225599841,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}