{"id":"W2086781393","doi":"10.1039/c4ra01542h","title":"Diastereodivergent total synthesis of mosquito oviposition pheromone","year":2014,"lang":"en","type":"article","venue":"RSC Advances","topic":"Chemistry and Chemical Engineering","field":"Environmental Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Pheromone; Yield (engineering); Diastereomer; Stereochemistry; Chemistry; Total synthesis; Organic chemistry; Biology; Botany; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002423712,0.0006986587,0.0002958939,0.0002202123,0.0001635912,0.0002050695,0.0003090945,0.0001839229,0.002132661],"category_scores_gemma":[0.0001159705,0.0002008471,0.0002695676,0.0002927336,0.0001411474,0.0002685602,0.0003433165,0.0005473942,0.001221687],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002153726,"about_ca_system_score_gemma":0.0004760224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004026967,"about_ca_topic_score_gemma":0.001067649,"domain_scores_codex":[0.9998859,0.00001303072,0.00001182041,0.00002571723,0.0000268295,0.00003665826],"domain_scores_gemma":[0.9999226,0.000008277044,0.00001295219,0.00001639377,0.00001706598,0.00002262234],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001082295,0.00004071461,0.0001020607,0.000165253,0.00001750977,0.0002050394,0.00005331616,0.0005345527,0.9887395,0.001122504,0.0002876313,0.008623702],"study_design_scores_gemma":[0.00001800014,0.0002102317,0.0004383717,0.000006873963,0.00001338516,0.0001668865,0.00001739777,0.0003567768,0.9903083,0.0001523379,0.008301263,0.00001024387],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9083887,0.00320463,0.06033824,0.0002488485,0.0002027547,0.0003016977,0.005366133,0.000584859,0.02136425],"genre_scores_gemma":[0.9508872,0.004071476,0.03183574,0.00009143631,0.00002184957,0.0001847926,0.00313496,0.0001455066,0.009627015],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002132661,"threshold_uncertainty_score":0.007134438,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003510303663375553,"score_gpt":0.1870567262233597,"score_spread":0.1835464225599841,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}