{"id":"W2086997450","doi":"10.1021/ja021156x","title":"Ammonium Cyanate Shows N−H···N Hydrogen Bonding, Not N−H···O","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nuclear Laboratories","funders":"","keywords":"Cyanate; Chemistry; Hydrogen bond; Cyanate ester; Neutron diffraction; Ammonium; Crystallography; Crystal structure; Hydrogen; Inorganic chemistry; Polymer chemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001813809,0.0001666725,0.0003007967,0.00001812861,0.0001276353,0.00003540108,0.0004578934,0.00007074438,0.0002611238],"category_scores_gemma":[0.000155137,0.000117978,0.001417422,0.0002900997,0.0003493577,0.00007417698,0.00007002552,0.0007184949,0.000002823549],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001489139,"about_ca_system_score_gemma":0.00007576519,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002376925,"about_ca_topic_score_gemma":0.000001500757,"domain_scores_codex":[0.9987571,0.00003383009,0.0003918551,0.0001548693,0.0003743598,0.0002879791],"domain_scores_gemma":[0.9986471,0.00009196853,0.0007029401,0.0003078845,0.0001018455,0.0001482423],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003919954,0.00009956413,0.0008865139,0.00001002519,0.0002670797,0.000005980629,0.0001399962,0.00003046138,0.9874821,0.0001343326,0.01061687,0.0002878906],"study_design_scores_gemma":[0.0002639682,0.00001675184,0.00003840673,0.00002565343,0.0001067249,0.000254778,0.0005640797,0.00003079467,0.8705733,0.0002238143,0.1277644,0.0001372787],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940046,0.0001078349,0.0001042086,0.0009345236,0.00008703602,0.00002434176,0.00001352753,0.00001852396,0.004705416],"genre_scores_gemma":[0.9963865,0.0000477895,0.001314151,0.001267796,0.0001593931,0.000002502797,0.000001127916,0.00002320688,0.000797499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1171475,"threshold_uncertainty_score":0.4811002,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009253689031111218,"score_gpt":0.2489593135649245,"score_spread":0.2397056245338133,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}