{"id":"W2087088685","doi":"10.1103/physrevlett.95.147402","title":"Anharmonic Couplings Underlying the Ultrafast Vibrational Dynamics of Hydrogen Bonds in Liquids","year":2005,"lang":"en","type":"article","venue":"Physical Review Letters","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":76,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Anharmonicity; Intermolecular force; Physics; Fermi resonance; Femtosecond; Hydrogen bond; Coupling (piping); Density functional theory; Atomic physics; Dimer; Molecular physics; Infrared; Materials science; Nuclear magnetic resonance; Quantum mechanics; Molecule; Laser","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001072827,0.0002286834,0.0001492526,0.0002913459,0.0003494554,0.0002450219,0.0004741051,0.0003399404,0.001241527],"category_scores_gemma":[0.000516246,0.0001955044,0.0001252845,0.0001573696,0.0006422756,0.0006904901,0.0004718978,0.000517217,0.0001353173],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002536023,"about_ca_system_score_gemma":0.0001348564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005215063,"about_ca_topic_score_gemma":0.0007140535,"domain_scores_codex":[0.9999309,0.000008701573,0.000002378292,0.00001726845,0.00002887264,0.00001196503],"domain_scores_gemma":[0.9998055,0.00009639115,0.00004498356,0.00001953135,0.0000150709,0.00001859794],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001620233,0.0001180879,0.004281774,0.0001745105,0.00003963674,0.0002124956,0.0005474472,0.0267785,0.9041932,0.03719589,0.0001902847,0.02610622],"study_design_scores_gemma":[0.00007449389,0.000335359,0.01635299,0.00004305183,0.00004198405,0.0004004063,0.0003597177,0.5858703,0.3376282,0.05710617,0.001703489,0.00008380679],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.961788,0.0003731666,0.03566349,0.0001005138,0.000008521679,0.0000133493,0.00004219915,0.00009209392,0.001918784],"genre_scores_gemma":[0.9956368,0.0001221687,0.003991994,0.00001008106,0.000003715917,0.00001143874,0.00001821762,0.000006750097,0.0001988162],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001241527,"threshold_uncertainty_score":0.004153371,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01899986070251065,"score_gpt":0.3024990877811042,"score_spread":0.2834992270785935,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}