{"id":"W2087512741","doi":"10.1002/(sici)1099-0690(200005)2000:9<1727::aid-ejoc1727>3.0.co;2-0","title":"Stable Heterotopic Noncovalent Resorcin[4]arene Assemblies","year":2000,"lang":"fr","type":"article","venue":"European Journal of Organic Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Trimer; Vapor pressure osmometry; Chloroform; Dimer; Titration; Osmometer; Non-covalent interactions; Dilution; Proton NMR; Polymer chemistry; Equilibrium constant; Crystallography; Stereochemistry; Organic chemistry; Physical chemistry; Vapor pressure; Molecule; Hydrogen bond","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008337139,0.0006623981,0.0007590228,0.00003480211,0.000220994,0.0002879268,0.001438379,0.0002258972,0.1651665],"category_scores_gemma":[0.0002281551,0.000720325,0.0006053835,0.0003355948,0.0002969753,0.0002978014,0.000207291,0.001496496,0.0006291753],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003434292,"about_ca_system_score_gemma":0.0003836772,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004614729,"about_ca_topic_score_gemma":6.085683e-7,"domain_scores_codex":[0.9959627,0.0002696049,0.001583548,0.0005554949,0.0008000342,0.0008286127],"domain_scores_gemma":[0.997111,0.0001210993,0.0008259139,0.001026016,0.0003019071,0.0006140531],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002107881,0.0005283229,0.0002963497,0.00110274,0.0004438651,0.004196227,0.0003649945,0.00008036943,0.9584502,0.00000347266,0.01471114,0.01961153],"study_design_scores_gemma":[0.001402995,0.00007102783,0.0000706499,0.0008084215,0.0001975186,0.003669378,0.0002570363,0.00001311952,0.5874817,0.00004628358,0.405542,0.0004398198],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7763075,0.02343379,0.0001277067,0.001233633,0.0004316958,0.00005293207,0.00004608685,0.00005504545,0.1983117],"genre_scores_gemma":[0.7877281,0.002590987,0.0007155801,0.0001800432,0.003762525,0.000001406199,0.00002815422,0.0001933972,0.2047998],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3908308,"threshold_uncertainty_score":0.9995248,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01495331680823045,"score_gpt":0.2208892794699056,"score_spread":0.2059359626616751,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}