{"id":"W2087604192","doi":"10.1021/om800889j","title":"Binuclear Organoplatinum(IV) Complexes with Bridging Xylenediyl Groups: Formation of Supramolecular Polymers through Hydrogen Bonding","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Hexafluorophosphate; Oxidative addition; Hydrogen bond; Steric effects; Bromide; Pyridine; Supramolecular polymers; Medicinal chemistry; Ligand (biochemistry); Supramolecular chemistry; Carboxylic acid; Polymer chemistry; Stereochemistry; Crystal structure; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002036895,0.0004740959,0.0007572371,0.0002227262,0.0002494069,0.0001140712,0.0005662842,0.0001590504,0.01213892],"category_scores_gemma":[0.00007396367,0.0004371415,0.0002676453,0.001089947,0.0001651969,0.0007299906,0.0001167891,0.0002286407,0.0000661803],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001404537,"about_ca_system_score_gemma":0.00006495165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000409462,"about_ca_topic_score_gemma":0.00001389391,"domain_scores_codex":[0.9973721,0.00003961226,0.0007584802,0.0005491655,0.0006904128,0.0005902601],"domain_scores_gemma":[0.9982908,0.00008301012,0.000519789,0.0008308669,0.0001172316,0.0001582361],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007594015,0.0002393443,0.0003612166,0.0001436452,0.0002479636,0.00001852223,0.001209261,0.00004212045,0.9802756,0.005319478,0.00003675425,0.0120302],"study_design_scores_gemma":[0.000948709,0.0001753617,0.0005509403,0.0001265122,0.0004764856,0.0001066533,0.001450089,0.0007256823,0.9821918,0.0007668632,0.01168773,0.0007931642],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9774985,0.0005484946,0.003706811,0.0004106859,0.00002595147,0.0001323648,0.00005828622,0.0002139166,0.01740493],"genre_scores_gemma":[0.9953292,0.0000730559,0.002718651,0.000201891,0.0001239301,0.000006026661,0.0002308017,0.00009815118,0.001218312],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01783062,"threshold_uncertainty_score":0.999808,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0117389439100699,"score_gpt":0.2125084130820249,"score_spread":0.200769469171955,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}