{"id":"W2087633976","doi":"10.1021/ma061604b","title":"Temperature-Sensitive Properties of Poly(<i>N</i>-isopropylacrylamide) Mesoglobules Formed in Dilute Aqueous Solutions Heated above Their Demixing Point","year":2006,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":134,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Aqueous solution; Poly(N-isopropylacrylamide); Microviscosity; Chemistry; Polymer; Fluorescence anisotropy; Lower critical solution temperature; Turbidimetry; Dynamic light scattering; Upper critical solution temperature; Pyrene; Analytical Chemistry (journal); Polymer chemistry; Materials science; Physical chemistry; Copolymer; Chromatography; Organic chemistry; Nanoparticle; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002850572,0.0003772702,0.0004027777,0.0001478467,0.0002010392,0.00004808869,0.0003156013,0.0002798739,0.000006832907],"category_scores_gemma":[0.0001305417,0.0003140623,0.0001836455,0.0002932624,0.0003646763,0.00001596084,0.000224627,0.0001924019,0.00001194439],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007857681,"about_ca_system_score_gemma":0.0001673584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001292514,"about_ca_topic_score_gemma":0.001345441,"domain_scores_codex":[0.9977872,0.0001780714,0.0006275928,0.0005920829,0.0002008726,0.0006141701],"domain_scores_gemma":[0.9989262,0.00002010489,0.0001850095,0.0005886232,0.0002005035,0.0000795883],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001145984,0.0001981589,0.0004114198,0.00004504032,0.00006995312,0.00001038645,0.0001932636,0.0001323054,0.9966598,0.0003948211,0.0002092574,0.001560953],"study_design_scores_gemma":[0.0004536412,0.0001012647,0.001496188,0.0001244083,0.00002892161,0.00006766141,0.000352672,0.0002562017,0.9951842,0.0005615362,0.0009865018,0.0003868195],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9877351,0.008377155,0.001178028,0.0006337799,0.00005866333,0.0006492651,0.0001391991,0.00006205805,0.00116675],"genre_scores_gemma":[0.9976304,0.0001857664,0.001186301,0.0001978118,0.0001084818,0.0001959593,0.0001594829,0.00006981475,0.0002660492],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009895232,"threshold_uncertainty_score":0.9999312,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01126456654240638,"score_gpt":0.2090296540182185,"score_spread":0.1977650874758121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}