{"id":"W2087635780","doi":"10.1021/ic302401m","title":"Molecular Recognition Using Ruthenium(II) Porphyrin Thiol Complexes as Probes","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Porphyrin; Steric effects; Tetraphenylporphyrin; Electronic effect; Ruthenium; Thiol; Stereochemistry; Molecule; Coordination complex; Metal; Photochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001298671,0.0002848944,0.0001849362,0.00009998922,0.0001526655,0.0002874566,0.0003704833,0.0003284969,0.0008851417],"category_scores_gemma":[0.0001638028,0.0001070133,0.00009712522,0.0001210106,0.0002340296,0.0001817973,0.0001599031,0.0003057462,0.000274756],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002607706,"about_ca_system_score_gemma":0.00005751849,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003834649,"about_ca_topic_score_gemma":0.0004811096,"domain_scores_codex":[0.9998665,0.0000280431,0.000003609385,0.00004508728,0.00002980542,0.00002702551],"domain_scores_gemma":[0.9999156,0.00002577313,0.0000224556,0.00001143231,0.00001145452,0.00001334608],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003666878,0.000006108491,0.00004245976,0.00002382554,0.000003505146,0.00001530259,0.00001503366,0.0002128145,0.9986144,0.00006864573,0.00004858778,0.0009126406],"study_design_scores_gemma":[0.000003498256,0.00005910168,0.0002620557,8.661086e-7,0.000004259934,0.00004101486,0.000008284206,0.0009088977,0.9978582,0.00002015576,0.0008310065,0.000002598007],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874529,0.001120046,0.008833031,0.00007885621,0.00002175771,0.00001363525,0.0001243991,0.0002299687,0.002125415],"genre_scores_gemma":[0.9904683,0.0006214086,0.005779529,0.00004144895,0.00001343874,0.00001660063,0.0002077581,0.00002619863,0.002825355],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008851417,"threshold_uncertainty_score":0.00296104,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01764081629846473,"score_gpt":0.2352963768441107,"score_spread":0.217655560545646,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}