{"id":"W2087665705","doi":"10.1021/jp066143a","title":"Optical and Photophysical Properties of Indolocarbazole Derivatives","year":2006,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Université Laval","funders":"","keywords":"Time-dependent density functional theory; Hypsochromic shift; Density functional theory; Chemistry; Photochemistry; Excited state; Fluorescence; Intersystem crossing; Quantum yield; Oscillator strength; Ground state; Absorption (acoustics); Absorption spectroscopy; Singlet state; Computational chemistry; Materials science; Atomic physics; Spectral line; Optics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006859268,0.00008232248,0.0001743173,0.000005932588,0.00001975831,0.000007350052,0.0001129899,0.00002749564,0.000003266694],"category_scores_gemma":[0.00001319165,0.00005066625,0.00005006801,0.00006518581,0.0001197984,0.00004207887,0.00002178,0.0002457998,4.262749e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001583487,"about_ca_system_score_gemma":0.00002034611,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002788642,"about_ca_topic_score_gemma":2.229673e-7,"domain_scores_codex":[0.9995568,0.000008998716,0.0001615201,0.00003369047,0.0001299231,0.0001090948],"domain_scores_gemma":[0.9997427,0.00005535312,0.00005396675,0.00007506784,0.00004163597,0.00003126263],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002331282,0.00005460899,0.000007237764,0.00005884226,0.00002852705,9.234807e-7,0.0001541216,0.002591392,0.9968424,0.0001234342,0.00004733297,0.00006783609],"study_design_scores_gemma":[0.0001676129,0.00005331581,0.00008830582,0.00003306535,0.0000301267,0.00002513446,0.00004167783,0.008862423,0.9894089,0.001168471,0.00006351408,0.0000575067],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986593,0.000482997,0.0001548702,0.00003587928,0.000006479745,0.00002387891,8.867084e-7,0.000008231801,0.0006274796],"genre_scores_gemma":[0.999671,0.00002464776,0.00001754998,0.000005048732,0.0002554723,5.051032e-7,2.082374e-7,0.00001053967,0.00001504087],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007433583,"threshold_uncertainty_score":0.206611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005017708548427501,"score_gpt":0.1770724346201904,"score_spread":0.1720547260717629,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}