{"id":"W2087676667","doi":"10.1021/om990669i","title":"Synthesis and Characterization of RuH<sub>2</sub>(H<sub>2</sub>)<sub>2</sub>(P<sup>i</sup>Pr<sub>3</sub>)<sub>2</sub> and Related Chemistry. Evidence for a Bis(dihydrogen) Structure","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":82,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Protonation; Chemistry; Hydride; Dimer; Dihydrogen complex; Octahedron; Crystallography; Atmosphere (unit); Crystal structure; Pentane; Hydrogen; Stereochemistry; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001792251,0.000201907,0.0002122048,0.0001958716,0.0001482755,0.0002676874,0.0002431999,0.0003024706,0.00133505],"category_scores_gemma":[0.0003754321,0.0001431284,0.00008331765,0.0001831342,0.0001512365,0.0001985782,0.0001609733,0.0002020236,0.0004724566],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000252724,"about_ca_system_score_gemma":0.000174198,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005595664,"about_ca_topic_score_gemma":0.0007757324,"domain_scores_codex":[0.9998847,0.00001493103,0.000007592584,0.00002149732,0.0000550229,0.00001616842],"domain_scores_gemma":[0.9998724,0.00002117847,0.00002927966,0.00002044469,0.00002974665,0.00002678497],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002968115,0.0000146092,0.00007455779,0.00003661339,0.00000140884,0.00004530728,0.00001501701,0.00008539334,0.9978498,0.00008569381,0.00007130167,0.001690593],"study_design_scores_gemma":[0.000007338007,0.0001297489,0.001511642,0.000003179911,0.000005272349,0.0001742602,0.00001220185,0.0005582944,0.992939,0.00005857803,0.004595532,0.000004844421],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9526088,0.002901186,0.03580185,0.0002177914,0.00005337319,0.0003385662,0.001440209,0.0004217907,0.006216544],"genre_scores_gemma":[0.9704403,0.0008150027,0.01948372,0.0001040549,0.00002099597,0.0000990412,0.001543197,0.00007785377,0.007415853],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00133505,"threshold_uncertainty_score":0.004466176,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01146772634920083,"score_gpt":0.2078129807203882,"score_spread":0.1963452543711874,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}