{"id":"W2087752221","doi":"10.1039/c4dt01949k","title":"Impact of constitutional isomerism on phosphorescence and anion-sensing properties of donor–acceptor organoboron Pt(<scp>ii</scp>) complexes","year":2014,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphorescence; Chemistry; Photochemistry; Acceptor; Fluoride; Ion; Fluorescence; Molecule; Titration; Platinum; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002508576,0.0002158144,0.0004042766,0.0001175359,0.0002949804,0.00004882252,0.0001645146,0.00009170672,0.0001834733],"category_scores_gemma":[0.00008478067,0.0001671002,0.0001013679,0.0001393958,0.001067494,0.0003040567,0.00001727642,0.00008936266,0.00002484754],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004527246,"about_ca_system_score_gemma":0.0001202636,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000514494,"about_ca_topic_score_gemma":0.00002402428,"domain_scores_codex":[0.9985642,0.00009501486,0.0004564663,0.0003118518,0.0002875337,0.0002849408],"domain_scores_gemma":[0.9991531,0.0001012827,0.0002108052,0.0002620115,0.0001660623,0.0001067046],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006437925,0.0001869282,0.001203044,0.0001033857,0.00001958552,4.36982e-7,0.000860306,0.0001444342,0.9963885,0.0005641907,0.0001324531,0.0003323743],"study_design_scores_gemma":[0.0004833408,0.0003811448,0.01144458,0.0001777247,0.00003696725,0.000014659,0.0001582004,0.0002049021,0.9867392,0.00005248567,0.0002100559,0.00009679568],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917663,0.0000988734,0.006996161,0.00005620786,0.0004341306,0.0002505754,0.0002139355,0.00005493928,0.0001288313],"genre_scores_gemma":[0.9989072,0.0000921608,0.0008225859,0.00002670714,0.00006782218,0.000005525766,0.00001387897,0.00001419359,0.00004990373],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01024154,"threshold_uncertainty_score":0.6814149,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01716870150397659,"score_gpt":0.2418999039210785,"score_spread":0.2247312024171019,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}