{"id":"W2087976338","doi":"10.1139/v04-170","title":"New cycloaddition of diarylazines with 1,2-dehydrobenzene, 1,1,2,2-tetracyanoethylene, and dibenzoylacetylene Facile synthesis of acridinones, pyrazolidine, and pyridazine derivatives","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Tetracyanoethylene; Chemistry; Pyridazine; Cycloaddition; Aryne; Yield (engineering); Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002238904,0.0002162932,0.0004795096,0.00006169187,0.00006297376,0.00002521816,0.0001771549,0.0001830647,0.001252112],"category_scores_gemma":[0.0005454689,0.0001641902,0.00007980483,0.0001237226,0.00023868,0.0001814261,0.00001783771,0.0001693163,5.141249e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006217959,"about_ca_system_score_gemma":0.0004699152,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003878039,"about_ca_topic_score_gemma":0.0006357117,"domain_scores_codex":[0.9987735,0.0000180845,0.0005560013,0.0001949065,0.0002282493,0.0002293128],"domain_scores_gemma":[0.9982526,0.0002967107,0.000584605,0.000166452,0.0002383767,0.000461264],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009231332,0.00003300725,0.008517285,0.0002695781,0.0001062151,0.000009781216,0.0001471944,0.00006403486,0.9489483,0.00001337561,0.0004200889,0.04137886],"study_design_scores_gemma":[0.000524084,0.00005001125,0.0105244,0.0004394274,0.0000863042,0.0001486154,0.0003192672,0.00005546719,0.9860591,0.0001048595,0.001500668,0.0001878233],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993672,0.003356666,0.00004922737,0.0005622986,0.00001343695,0.00003574189,0.0001350415,0.000005954165,0.002169611],"genre_scores_gemma":[0.9975716,0.0006516494,0.001352657,0.00001914242,0.0002441612,0.000002893815,0.00001118367,0.00001712147,0.0001295232],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04119104,"threshold_uncertainty_score":0.9996608,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009652228609745113,"score_gpt":0.2042935952969698,"score_spread":0.1946413666872247,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}