{"id":"W2087976338","doi":"10.1139/v04-170","title":"New cycloaddition of diarylazines with 1,2-dehydrobenzene, 1,1,2,2-tetracyanoethylene, and dibenzoylacetylene Facile synthesis of acridinones, pyrazolidine, and pyridazine derivatives","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Tetracyanoethylene; Chemistry; Pyridazine; Cycloaddition; Aryne; Yield (engineering); Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001447693,0.0003468306,0.0001800587,0.0001677316,0.000109429,0.0001852863,0.0002198471,0.0001862787,0.00115179],"category_scores_gemma":[0.0001070955,0.0001868376,0.000142753,0.0001066264,0.0001720945,0.0002144536,0.0001534258,0.0003727447,0.0002568715],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003370997,"about_ca_system_score_gemma":0.0002045186,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004665609,"about_ca_topic_score_gemma":0.002070018,"domain_scores_codex":[0.9999135,0.00001232278,0.000007092567,0.00001763027,0.00002385935,0.00002561657],"domain_scores_gemma":[0.9999251,0.00001315562,0.00002390382,0.000008032412,0.0000101062,0.00001956671],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003918331,0.00002347957,0.00007439395,0.00005450038,0.000004575624,0.00009298436,0.00002898247,0.00009300236,0.9971107,0.0003714729,0.0000505659,0.002056175],"study_design_scores_gemma":[0.00002033339,0.000252786,0.0007338964,0.000002798729,0.000008654211,0.000218799,0.000007131167,0.0002758215,0.9940966,0.00002850003,0.004349642,0.00000501068],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9727898,0.004115175,0.0135362,0.000133493,0.00010952,0.0001693665,0.0003251073,0.0001948321,0.008626402],"genre_scores_gemma":[0.982004,0.001888002,0.00979506,0.00004556058,0.00001378336,0.0000668845,0.0002539915,0.00001499385,0.005917727],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00115179,"threshold_uncertainty_score":0.003853142,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009652228609745113,"score_gpt":0.2042935952969698,"score_spread":0.1946413666872247,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}